钝感推进剂用粘合剂的共聚改性研究进展  

Copolymerization Modification of Binders for Insensitive Propellants

作　　者：李文希 许伟春 苏学 李雅楠 郑文芳[1] LI Wen-xi;XU Wei-chun;SU Xue;LI Ya-nan;ZHENG Wen-fang(School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China;Shanghai Academy of Spaceflight Technology,Shanghai 201109,China;Suzhou New Century Testing Technology Service Corporation Limited,Jiangsu Suzhou,215124,China)

机构地区：[1]南京理工大学化学与化工学院,南京210094 [2]上海航天技术研究院,上海201109 [3]苏州新世纪检测技术服务有限公司,江苏苏州215124

出　　处：《装备环境工程》2022年第10期26-35,共10页Equipment Environmental Engineering

基　　金：上海航天科技创新基金(SAST2018-106)。

摘　　要：主要从线性共聚和星形共聚2方面综述了对现有聚醚类粘合剂共聚改性以及合成新型粘合剂的研究进展。探讨了共聚作用特别是嵌段共聚通过调节分子链的序列结构来改善聚合物性能的有效方法,以及星形共聚物特殊的超支化分子结构对聚合物性能的影响。希望能为兼具高能量与低感度固体推进剂用粘合剂的设计开发提供新思路和技术支撑。The paper reviews the research progress on the copolymerization modification of existing binders and the synthesis of new binders from two aspects of linear copolymerization and star copolymerization. This paper discusses the effective ways of copolymerization, especially block copolymerization, to improve copolymer properties by modulating the sequence structure of molecular chains, and the effect of the special hyperbranched molecular structure of star copolymers on copolymer properties. It is expected to provide new ideas and technical support for the design and development of binders for solid propellants with both high energy and low sensitivity.

关 键 词：低易损 推进剂 共聚改性 粘合剂 力学性能 感度 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] TQ430.7[化学工程]