氮氧化富氮骨架的含能材料合成研究进展  

Research Progress in the Synthesis of Energetic Materials Based on Nitrogen-rich N-oxide Skeletons

作　　者：郭元盛 吕玺 李洋[1] 薛祺[1] 弥阳丽[1] 崔伟 南少聪 刘鹏[1] 张萌 GUO Yuan-sheng;Lü Xi;LI Yang;XUE Qi;MI Yang-li;CUI Wei;NAN Shao-cong;LIU Peng;ZHANG Meng(Xi'an Modern Chemistry Research Institute,Xi'an 710065,China;Bureau of Military Representative of the PLA in the 845 Factory,Xi'an 710302,China;Bureau of Military Representative of the PLA in Xi'an,Xi'an 710065,China)

机构地区：[1]西安近代化学研究所,陕西西安710065 [2]中国人民解放军驻845厂军代室,陕西西安710302 [3]陆装驻西安地区航空军事代表室,陕西西安710065

出　　处：《火炸药学报》2022年第5期629-638,共10页Chinese Journal of Explosives & Propellants

基　　金：国家自然科学基金(No.21805223)。

摘　　要：综述了基于氮氧化富氮骨架的含能材料合成研究进展,以单环型、串联型及并联型分子骨架结构进行分类,重点围绕N-氧化物片段的引进策略进行比较,表明并联型富氮芳环N-氧化物的骨架合成难度最大,但往往能够获得较串联型与单环型氮氧化富氮骨架更为致密的结构。通过将直接氮氧化引进策略与环化氮氧化引进策略同时进行分析讨论,阐释了不同骨架结构的N-氧化物含能材料构建的设计思路。在此基础上,进一步比较了相关化合物的合成方法并对代表性化合物的性能进行了评估。附参考文献61篇。The research progress in the synthesis of energetic materials with nitrogen-rich N-oxide skeletons was reviewed.The compounds were classified by monocyclic,tandemed and fused molecular skeletons.Focusing on the comparison of the introduction strategies of N-oxide fragments,it is proved that the skeleton synthesis of fused nitrogen-rich aromatic N-oxides is more difficult,but often gives denser structures than tandem and monocyclic nitrogen-rich N-oxides.The direct nitrogen oxidation introduction strategy and the cyclic nitrogen oxidation introduction strategy were analyzed and discussed,providing a reference for the design of nitrogen-rich N-oxides with different skeleton structures.In addition,the synthesis methods of related compounds were further compared and the properties of representative compounds were evaluated.With 61 references.

关 键 词：含能材料 氮氧化反应 N-氧化物 合成 性能 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] TQ56[化学工程—炸药化工]