过渡金属磷化物的加氢性能研究进展  

Research progress on hydrogenation properties of transition metal phosphide

作　　者：陆雪峰 隋晓东 丰铭 刘玉佩 刘彦峰 Lu Xuefeng;Sui Xiaodong;Feng Ming;Liu Yupei;Liu Yanfeng(PetroChina Petrochemical Research Institute Daqing Petrochemical Research Center,Daqing 163714,China;PetroChina Daqing Refining&Chemical Company Refinery,Daqing 163411,China)

机构地区：[1]中国石油石油化工研究院大庆化工研究中心,黑龙江大庆163714 [2]中国石油大庆炼化公司,黑龙江大庆163411

出　　处：《炼油与化工》2022年第5期16-20,共5页Refining And Chemical Industry

摘　　要：过渡金属磷化物由于具有与过渡金属氮化物和碳化物相似的物理性质,成为新型催化材料研究领域的热点,文中论述了过渡金属磷化物的结构特征、制备方法和加氢催化性能方面的研究进展,着重介绍了其加氢脱硫、脱氮、脱氧和加氢异构的性能,研究表明,过渡金属磷化催化剂,尤其是Ni2P的加氢活性优于传统的硫化物催化剂,并具有媲美贵金属催化剂的良好异构选择性和活性,且具有良好的抗中毒能力,具有潜在应用前景。Transition metal phosphide,which has the similar physical properties as transition metal nitrides and carbides,becomes a research hotspot in the field of new catalytic materials.This paper discussed the structural characteristics of the transition metal phosphide,preparation methods and research progress of hydrogenation catalyst performance,emphatically introduced its properties of the hydrogenation desulfurization,denitrification,deoxidization and hydroisomerization.Research had shown that the hydrogenation activity of transition metal phosphating catalysts,especially Ni_(2)P,was better than that of traditional sulfide catalysts,and had better heterogeneous selectivity and activity than noble metal catalysts,and had good anti-poisoning ability,which had potential application prospects.

关 键 词：过渡金属磷化物 加氢脱硫 加氢脱氮 加氢脱氧 加氢异构 

分 类 号：TQ426.8[化学工程]