Vertical distribution and temporal evolution of formaldehyde and glyoxal derived from MAX-DOAS observations:The indicative role of VOC sources  

作　　者：Qianqian Hong Cheng Liu Qihou Hu Yanli Zhang Chengzhi Xing Jinping Ou Wei Tan Haoran Liu Xiaoqing Huang Zhenfeng Wu 

机构地区：[1]School of Environment and Civil Engineering,Jiangnan University,Wuxi 214122,China [2]Center for Excellence in Regional Atmospheric Environment,Institute of Urban Environment,Chinese Academy of Sciences,Xiamen 361021,China [3]Key Lab of Environmental Optics&Technology,Anhui Institute of Optics and Fine Mechanics,Hefei Institutes of Physical Science,Chinese Academy of Sciences,Hefei 230031,China [4]Department of Precision Machinery and Precision Instrumentation,University of Science and Technology of China,Hefei 230026,China [5]Anhui Province Key Laboratory of Polar Environment and Global Change,University of Science and Technology of China,Hefei 230026,China [6]Guangdong Key Laboratory of Environmental Protection and Resources Utilization,State Key Laboratory of Organic Geochemistry,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640,China [7]Guangdong-Hongkong-Macao Joint Laboratory of Collaborative Innovation for Environmental Quality,Guangzhou 510632,China [8]Institute of Physical Science and Information Technology,Anhui University,Hefei 230601,China

出　　处：《Journal of Environmental Sciences》2022年第12期92-104,共13页环境科学学报（英文版）

基　　金：the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA23020301);the National Natural Science Foundation of China(Nos.51778596,41977184,and 41941011);the Key Research and Development Project of Anhui Province(202104i07020002);the Anhui Science and Technology Major Project(No.18030801111);the Major Projects of High Resolution Earth Observation Systems of National Science and Technology(05-Y30B01-9001-19/20-3);the Youth Innovation Promotion Association of CAS(2021443);the Young Talent Project of the Center for Excellence in Regional Atmospheric Environment,CAS(CERAE202004);the Fundamental Research Funds for the Central Universities(No.JUSRP12042)。

摘　　要：Formaldehyde(HCHO)and glyoxal(CHOCHO)are important oxidization intermediates of most volatile organic compounds(VOCs),but their vertical evolution in urban areas is not well understood.Vertical profiles of HCHO,CHOCHO,and nitrogen dioxide(NO_(2))were retrieved from ground-based Multi-Axis Differential Optical Absorption Spectroscopy(MAXDOAS)observations in Hefei,China.HCHO and CHOCHO vertical profiles prefer to occur at higher altitudes compared to NO_(2),which might be caused by the photochemistry-oxidation of longer-lived VOCs at higher altitudes.Monthly means of HCHO concentrations were higher in summer,while enhanced amounts of NO_(2)were mainly observed in winter.CHOCHO exhibited a hump-like seasonal variation,with higher monthly-averaged values not only occurred in warm months(July-August)but also in cold months(November-December).Peak values mainly occurred during noon for HCHO but emerged in the morning for CHOCHO and NO_(2),suggesting that HCHO is stronger link to photochemistry than CHOCHO.We further use the glyoxal to formaldehyde ratio(GFR)to investigate the VOC sources at different altitudes.The lowest GFR value is almost found in the altitude from 0.2 to 0.4 km,and then rises rapidly as the altitude increases.The GFR results indicate that the largest contributor of the precursor VOC is biogenic VOCs at lower altitudes,while at higher altitudes is anthropogenic VOCs.Our findings provide a lot more insight into VOC sources at vertical direction,but more verification is recommended to be done in the future.

关 键 词：FORMALDEHYDE GLYOXAL MAX-DOAS Vertical distribution VOC 

分 类 号：X701[环境科学与工程—环境工程]