表面活性离子液体参与构筑的胶束体系  

Micelle Systems Based on Surface Active Ionic Liquids

作　　者：赵学艳 肖瑞杰 曹桂荣 Zhao Xueyan;Xiao Ruijie;Cao Guirong(School of Ecology and Environment,Institute of Disaster Prevention,Sanhe,065201;Hebei Key Laboratory of Earthquake Dynamics,Sanhe,065201)

机构地区：[1]防灾科技学院生态环境学院,三河065201 [2]河北省地震动力学重点实验室,三河065201

出　　处：《化学通报》2022年第10期1209-1218,共10页Chemistry

基　　金：廊坊市科技局科学技术研究与发展计划项目(2021011041);中央高校基本科研业务费专题项目(ZY20215158)资助。

摘　　要：离子液体(ILs)的可设计性,使得新型表面活性离子液体(SAILs)不断涌现,从而将具有不同功能基团的ILs引入到了传统的有序分子聚集体中,这也将有助于实现有序分子聚集体的可控性和功能化。本文综述了SAILs在水溶液及离子液体中的胶束化行为,重点总结了烷基碳链长度、阴离子类型和阳离子结构对SAILs聚集行为的影响,分类归纳了SAILs与传统表面活性剂复配体系的协同增效作用,并探讨了SAILs构建的胶束体系的发展方向。Due to the designability of ionic liquids, new kinds of surface active ionic liquids(SAILs) continue to spring up. It is helpful to achieve the controllability and functionalization of ordered molecular aggregates by introducing different functional groups into ionic liquids. In this paper, the micellization of SAILs in aqueous solution and ionic liquids is reviewed. The effects of alkyl carbon chain length, anion types and cation structure of SAILs on the aggregation behavior are discussed in detail. The synergistic effect of the compound systems composed of SAILs and conventional surfactants is summarized. Finally, the future development of micelle systems based on SAILs is prospected.

关 键 词：表面活性离子液体 胶束 聚集行为 表面活性剂 

分 类 号：O645.1[理学—物理化学]