Crystalline,Rheological and Mechanical Enhancement in PBAT/PPC/Silica Nanocomposites with Double Percolation Network  

作　　者：You-Mei Ma Feng-Xiang Gao Shu-Ling Zhang 

机构地区：[1]College of Chemistry,Jilin University,Changchun,130012,China [2]Key Laboratory of Polymer Ecomaterials,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,130022,China

出　　处：《Chinese Journal of Polymer Science》2022年第11期1482-1492,共11页高分子科学（英文版）

基　　金：financially supported by Jilin Province Industrial Technology Research and Development Project(No.2021C0361);Jilin Province Science and Technology Development Program of China(No.20200501004GX)。

摘　　要：Nanocomposites of blends of biodegradable poly(butylene adipate-co-terephthalate)(PBAT)and sustainable poly(propylene carbonate)(PPC)with nanosilica were prepared by melt compounding method.PBAT/PPC blend was partially miscible system with sea-island structure,and nanosilica particles were selectively dispersed in the continuous phase PBAT matrix to form the double percolation network.The introduction of nanosilica into PBAT/PPC blend reduced the size of dispersed PPC phase,promoted the crystallization of PBAT in the nanocomposites,and increased the storage modulus of the nanocomposites.The study of rheological behaviors indicated that the double percolation network was formed at the nanosilica loading of 5 wt%,as a result,the nanocomposites exhibited the solid-like viscoelastic behavior and their relaxation time was extended.With the increase of the nanosilica content,the PBAT/PPC/silica nanocomposites displayed increased Young's modulus and yield strength.

关 键 词：NANOCOMPOSITES Selective dispersion Double percolation Enhanced properties 

分 类 号：TB332[一般工业技术—材料科学与工程]