吡啶基卟啉的合成及表征  

Synthesis and Characterization of Pyridine-based porphyrin

作　　者：杨立国[1,2] 夏祥林 卢文欣 YANG Li-guo;XIA Xiang-lin;LU Wen-xin(Department of Chemical and Environmental Engineering,Anyang Institute of Technology,Henan Anyang 455000;School of Chemistry and Biological Engineering,Shandong University of Science and Technology,Shandong Qingdao 266590,China)

机构地区：[1]安阳工学院化学与环境工程学院,河南安阳455000 [2]山东科技大学化学与生物工程学院,山东青岛266590

出　　处：《广州化工》2022年第19期34-36,共3页GuangZhou Chemical Industry

基　　金：河南省自然科学基金项目(No:202300410010);安阳工学院2017年校科研基金项目(No:YJJ2016014)。

摘　　要：卟啉类的化合物将广泛应用于我们的日常生活中。卟啉化合物是由于其特殊的生物学意义和能够应用于人工光合作用,非线性光学零件及传感器等而产生的。人们正在广泛研究它的优化合成及应用方面,如新型手性卟啉结合锌等金属元素后,具有对半胱氨酸的特殊识别作用。本文合成了一种吡啶基卟啉化合物1,并通过核磁共振谱、荧光光谱和紫外光谱等手段对其进行了表征。The compounds of the porphyrin class will be widely used in our daily life. Porphyrin compounds are produced due to their special biological significance and can be applied to artificial photosynthesis, nonlinear optical parts and sensors. Its optimal synthesis and application were being widely studied, such as the new chiral porphyrin combined with zinc and other metal elements, which had a special recognition role of cysteine. A pyridine-based porphyrin compound 1 was synthesized and characterized by NMR, fluorescence and UV spectroscopy.

关 键 词：吡啶基卟啉 合成 表征 荧光 

分 类 号：O074.16[理学]