Dielectric dispersion and thermodynamic behavior of stearic acid binary mixtures with alcohol as co-solvent using time domain reflectometry  

作　　者：M.Maria Sylvester T.Ganesh D.J.S.Anand Karunakaran P.Senthilkumar Praveen G.Hudge A.C.Kumbharkhane 

机构地区：[1]PG&Research Department of Physics,Bishop Heber College,Bharthidasan University Tiruchirapalli 620017,Tamil Nadu,India [2]PG&Research Department of Physics,Rajah Serfoji Government College Bharthidasan University Thanjavur 613005,Tamil Nadu,India [3]Department of Physics,Saranathan College of Engineering Tiruchirapalli 620012,Tamil Nadu,India [4]Department of Physics,S.I.C.E.Society's Degree College of Arts Science and Commerce,Ambernath,Thane,Maharashtra,India [5]School of Physical Sciences,Swami Ramanad Teerth Marthwada University Nanded,Maharashtra,India

出　　处：《Journal of Advanced Dielectrics》2017年第4期34-40,共7页先进电介质学报（英文）

摘　　要：Dielectric permittivity and relaxation dynamics of binary and ternary mixture of stearic acid on various concentration and their thermodynamic effects are studied.The static dielectric constant(ε_(0)),dielectric permittivity(ε′)and dielectric loss(ε″)are found by bilinear calibration.The relaxation time(τ),dielectric strength(Δε)and the excess permittivity(ε^(E))are found.The thermodynamic parameters such as enthalpy(ΔH),entropy(ΔS)and Gibb's free energy(ΔG)are evolved.The significant changes in dielectric parameters are due to the intramolecular and intermolecular interactions in response to the applied frequency.The permittivity spectra of stearic acid–alcohol in the frequency range of 10MHz to 30 GHz have been measured using picoseconds Time Domain Reflectometry(TDR).The dielectric parameters(ε_(0),ε′,ε″)are found by bilinear calibration method.Influence of temperature in intermolecular interaction and the relaxation process are also studied.The FT-IR spectral analysis reveals that the conformation of functional groups and formation for hydrogen bonding are present in both binary and ternary mixtures of stearic acid.

关 键 词：TDR dielectric relaxation stearic acid thermodynamic parameters FT-IR 

分 类 号：TG1[金属学及工艺—金属学]