Recent advances in the synthesis and energetic properties of potassium-based potential green primary explosives  

作　　者：Qamar-un-Nisa Tariq Saira Manzoor Maher-un-Nisa Tariq Wen-Li Cao Jian-Guo Zhang 

机构地区：[1]State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,Beijing,100081,China [2]Department of Chemistry,University of Okara,Okara,56300,Pakistan

出　　处：《Defence Technology（防务技术）》2022年第11期1945-1959,共15页Defence Technology

基　　金：the NSAF (U1830134);NSFC (22175025), for their generous financial support;supported by a project of State Key Laboratory of Explosion Science and Technology (Beijing Institute of Technology). The project number is YBKT21-02

摘　　要：Primary explosives are utilized as a reliable initiator for secondary explosives in an extensive range of military and civilian operations. Heavy-metal-based primary explosives are moderate performing, more sensitive, and environmentally hazardous, posing a direct and indirect threat to health and safety.Therefore, heavy-metal-based primaries have been replaced by environment-friendly metal-based primary explosives, such as potassium complexes. This review presents not only a summary of the current progress of new-generation potassium-based primary explosives and their methods of preparation, energetic properties, and applications, but also a further comparison with traditional primary explosives. In addition, this work discusses the necessity of heavy metal-free primary explosives and the major challenges faced in replacing traditional primary explosives.

关 键 词：Green primary explosives Heterocyclic compounds SYNTHESIS Energetic properties 

分 类 号：TQ563[化学工程—炸药化工]