对位芳纶纳米纤维用量对对位芳纶纸结构及性能的影响  

Effect of the Amount of Para-aramid Nanofiber on the Structure and Properties of Para-aramid Paper

作　　者：董志荣 陈玥溪 刘余田 田伟 张云奎 姚坤承 庹新林 DONG Zhirong;CHEN Yuexi;LIU Yutian;TIAN Wei;ZHANG Yunkui;YAO Kuncheng;TUO Xinlin(Shandong Jufang New Materials Co.,Ltd.,Binzhou,Shandong Province,256500;Key Lab of Advanced Materials(MOE),Department of Chemical Engineering,Tsinghua University,Beijing,100084)

机构地区：[1]山东聚芳新材料股份有限公司,山东滨州256500 [2]清华大学化工系,教育部先进材料重点实验室,北京100084

出　　处：《中国造纸》2022年第11期11-17,共7页China Pulp & Paper

基　　金：国家自然科学基金(52073154);山东省重点研发计划(重大科技创新工程)项目(2019TSLH0109);清华大学(化工系)-黄河三角洲京博化工研究院有限公司高性能高分子材料联合研究中心基金。

摘　　要：本研究以原位聚合法制备的对位芳纶纳米纤维及市售对位芳纶沉析纤维为黏结纤维,分别与对位芳纶短切纤维混合,通过湿法抄造制备对位芳纶纸(纳米纸和沉析纸)。详细研究了2种不同原料及其用量对纸张结构及性能的影响规律,并对作用机理进行了探讨。结果表明,采用对位芳纶纳米纤维制备的纳米纸在纸张匀度、机械强度、电气绝缘强度等方面均优于对位芳纶沉析纤维制备的沉析纸。黏结纤维含量均为40%时,纳米纸抗张指数比沉析纸提高了44%,撕裂指数提高了57%,电击穿强度提高了80%。这种差异主要来源于对位芳纶纳米纤维具有更高的表面活性,以及由此产生良好的可加工性及二次组装性能。Para-aramid nanofibers prepared by in situ-polymerization method and commercial para-aramid fibrid were used as adhesive fibers,and mixed with para-aramid short-cut fibers to fabricate para-aramid paper by wet process,respectively. The effects of nanofiber and fibrid with their amount on the structure and properties of paper were studied in detail,and the reaction mechanism of which was also discussed. The results showed that the paper formation,mechanical strength and electrical insulation strength of para-aramid nanofiber paper were better than fibrid paper. With the content of nanofiber or fibrid at 40% in paper,the tensile and tear indexes of para-aramid nanofiber paper were 44% and 57% higher than those of fibrid paper,respectively. Moreover,the electrical breakdown strength of para-aramid nanofiber paper increased 80%. The difference was mainly due to the higher surface activity of para-aramid nanofibers,resulting a good machinability and secondary assembly performance.

关 键 词：芳纶纸 纳米纤维 沉析纤维 结构 性能 

分 类 号：TS761.2[轻工技术与工程—制浆造纸工程]