吸附除氟氧化铝改性研究进展  

Research Progress in Modification of Alumina for Adsorption Defluorination

作　　者：赵晓钰 宋兆阳 乔庆东[1] 刘全杰 徐会青 ZHAO Xiao-yu;SONG Zhao-yang;QIAO Qing-dong;LIU Quan-jie;XV Hui-qing(School of Petrochemical Engineering,Liaoning Liaoning Petrochemical University,Fushun Liaoning 113000,China;Sinopec Dalian Research Institute of Petroleum and Petrochemicals,Liaoning Dalian 116045,China)

机构地区：[1]辽宁石油化工大学石油化工学院,辽宁抚顺113000 [2]中国石油化工股份有限公司大连石油化工研究院,辽宁大连116045

出　　处：《当代化工》2022年第9期2166-2170,共5页Contemporary Chemical Industry

基　　金：中国石化重点科技项目,TBA高效加氢精制催化剂开发(项目编号:420014)。

摘　　要：近些年来,氧化铝由于其高比表面积、高活性、稳定性好的优点逐渐成为主要的除氟吸附材料,而改性后的氧化铝因具有更多活性位点成为除氟研究热点。介绍了几种除氟方法以及氧化铝除氟的机理,总结了金属改性(碱土金属、过渡金属、稀土金属)和表面活化在吸附除氟氧化铝改性中的研究进展,并对未来吸附除氟氧化铝改性发展方向提出展望。In recent years,alumina has gradually become the main adsorption material for fluorine removal because of its high specific surface area,high activity and good stability,while modified alumina has become the focus of fluorine removal research because of its more active sites.In this paper,several methods of fluoride removal and the mechanism of fluoride removal by alumina were introduced,the research progress of metal modification(alkaline earth metal,transition metal,rare earth metal)and surface activation in the modification of adsorption fluoride removal from alumina was summarized,and the development direction of adsorption fluoride removal by alumina was prospected.

关 键 词：氧化铝 除氟 吸附剂 金属改性 表面活化 

分 类 号：TQ133.1[化学工程—无机化工]