Optical,thermal and luminescence properties of La2O3-Ga2O3-ZrO2 glasses co-doped with Tm3+/Yb3+prepared by containerless technique  

作　　者：Jiansheng Xie Minghui Zhang Yanzhuo Wang Rongting Guo Ying Shi Xiuhong Pan Xuechao Liu Kun Chen Meibo Tang Feng Wu Zhihong Zhang 

机构地区：[1]School of Materials Science and Engineering,Shanghai University,Shanghai 200444,China [2]State Key Laboratory of High Performance Ceramics and Superfine Microstructure,Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai 200050,China [3]Hubei Key Laboratory of Plasma Chemistry and Advanced Materials,Wuhan Institute of Technology,Wuhan 430205,China [4]College of Chemical and Biological Engineering,Guilin University of Technology,Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials,Guilin 541004,China [5]AECC-Chengdu,Chengdu 610500,China

出　　处：《Journal of Rare Earths》2022年第11期1706-1714,I0002,共10页稀土学报（英文版）

基　　金：Project supported by the Youth Innovation Promotion Association,the Chinese Academy of Sciences(2020256);the Key Equipment Research Program,CAS(YJKYYQ20190008);the Science and Technology Committee of Shanghai(19142200400,20QA1410300);the National Natural Science Foundation of China(51602330,51472263);the Science and Technology Innovation Action Project of Science and Technology Committee of Shanghai(20511107400,19DZ1100703,20511107404)。

摘　　要：Bulk LaO-GaO-ZrO(LGZ)glass and Tm/Ybco-doped LGZ glasses were synthesized successfully using containerless technique.Raman spectra result reveals that the matrix sample possesses the low maximum phonon energy of~642 cm.The glasses show good compatibility between large Abbe numbers(>31)and high refractive indices(n>1.93).Moreover,transmittance measurements reflect that the glasses have high infrared transmittance of-81.9%,small OHabsorption coefficient and long mid-infrared cut-off wavelengths(-7.5μm).The surface morphology of host glass was characterized by scanning electron microscopy(SEM)micrograph and energy dispersive spectroscopy(EDS)tests reflect that the doped compositions are distributed into the matrix glass homogeneously.The results of thermal analysis show that the glasses have good thermal properties(T>769℃).Excited by 980 am laser,an intense 1810 am fluorescence is obtained originating from the transition:~3 E→~3 Hof Tmion,accompanied by upconversion emission.It can be observed that 1810 nm fluorescence has the highest intensity at 1 mol%YbOand owns broad full width at half-maximum(>245 nm),the luminescence intensity of~3 F→~3 Htransition increases with rising temperature from 300 to 550 K.Furthermore,the value of energy transfer efficiency shows that Ybcan transfer energy to Tmeffectively.By fitting the attenuation curves,the lifetimes of 1810 and 474 nm emission can be acquired.

关 键 词：Containerless technique Lanthanum gallate glass Thermal analysis LUMINESCENCE Rare earth ions 

分 类 号：TQ171.1[化学工程—玻璃工业]