Zr-MOFs及其衍生物用于CO_(2)加氢制甲醇的研究进展  

Research progress on application of Zr-MOFs and derivatives in CO_(2)hydrogenation to methanol

作　　者：杨学磊 左俊怡 纳薇[1] 高文桂[1] YANG Xue-lei;ZUO Jun-yi;NA Wei;GAO Wen-gui(Engineering Research Centre of Energy Conversion and Emission Reduction for Metallurgy of the Ministry of Education,Faculty of Metallurgical and Energy Engineering,Kunming University of Science and Technology,Kunming 650093,China)

机构地区：[1]昆明理工大学教育部冶金节能与减排工程研究中心,昆明理工大学冶金与能源工程学院,云南昆明650093

出　　处：《现代化工》2022年第11期22-26,32,共6页Modern Chemical Industry

基　　金：云南省应用基础研究计划(2019FB079);国家自然科学基金项目(51404122,51404099)。

摘　　要：综述了Zr-MOFs催化剂的制备方法并探讨了影响催化剂性能的因素;总结了近年来对Zr-MOFs催化剂进行离子掺杂、改变活性金属的位置、功能基团的改性修饰、改变活性组分、MOFs热解或部分热解等改性后催化剂在CO加氢制甲醇反应中的应用及反应机理;提出了目前存在的问题及未来的发展方向。The preparation methods of Zr-MOFs catalysts are reviewed,and the factors affecting the performance of Zr-MOFs catalysts are explored.The application of Zr-MOFs catalysts modified by various methods,such as ion doping,changing the position of active metal,modification of functional groups,changing the active component,and pyrolysis or partial pyrolysis of MOFs,in COhydrogenation to methanol reaction in recent years are mainly reviewed,and the reaction mechanism is also summarized.The existing problems and future development directions are proposed.

关 键 词：Zr-MOFs CO_(2) 甲醇 UiO-66 金属-载体相互作用 

分 类 号：TQ214[化学工程—有机化工]