Industry-compatible covalent organic frameworks for green chemical engineering  

作　　者：Zhifang Wang Qianqian Zhu Jiaxi Wang Fazheng Jin Penghui Zhang Dong Yan Peng Cheng Yao Chen Zhenjie Zhang 

机构地区：[1]State Key Laboratory of Medicinal Chemical Biology,College of Chemistry,Nankai University,Tianjin 300071,China [2]Key Laboratory of Advanced Energy Materials Chemistry,Ministry of Education,Nankai University,Tianjin 300071,China [3]Renewable Energy Conversion and Storage Center,Nankai University,Tianjin 300071,China [4]Frontiers Science Center for New Organic Matter,Nankai University,Tianjin 300071,China [5]College of Pharmacy,Nankai University,Tianjin 300071,China

出　　处：《Science China Chemistry》2022年第11期2144-2162,共19页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(22001131);the Frontiers Science Center for New Organic Matter of Nankai University(63181206);111 Projects(B12015);the Postdoctoral Science Foundation of China(2019M660974)。

摘　　要：In order to move towards sustainable development, the discovery of energy-efficient and environmentally friendly materials has become increasingly imperative. Covalent organic frameworks(COFs) as emerging designable crystalline porous materials have captured increasing attention for a wide array of clean-energy and environmental applications, attributed to their attractive advantages of low density, high surface area, adjustable and periodic pores, and functional skeletons. This review attempts to highlight the key advancements made in the green synthesis of COFs, processing of COFs, energy and environment-related applications, including gas storage, water treatment, the separation of gas mixture and organic molecules, catalysis, supercapacitors, fuel cell, and rechargeable batteries. Finally, a perspective regarding the remaining challenges and future directions on the synthesis and promising application for green chemical engineering of COFs has also been presented based on current achievements.

关 键 词：covalent organic frameworks green chemical engineering clean energy environmental protection 

分 类 号：TB383.4[一般工业技术—材料科学与工程]