N-磺酰基Pictet-Spengder反应制备1-苯基异喹啉的合成研究  

Study on the synthesis of 1-Phenylisoquinoline

作　　者：豆静杰 樊迪 焦聪宣 康长瑞 DOU Jingjie;FAN Di;JIAO Congxuan;KANG Changrui(China Lucky Film Group Co.,Ltd.,Baoding,Hebei 071002,China)

机构地区：[1]中国乐凯集团,河北保定071054

出　　处：《信息记录材料》2022年第10期18-20,共3页Information Recording Materials

摘　　要：1-苯基异喹啉具有刚性结构和较大的共轭体系,可以使发射光谱产生红移以提高红发光纯度,是OLED磷光染料的优良配体。使用苯乙胺和苯甲醛为原料,经N-磺酰基P-S三步反应制备出1-苯基异喹啉,结果表明其纯度可达到98.5%。1-phenylisoquinoline has a rigid structure and a large conjugate system,which can make the emission spectrum red-shift and improve the red luminescence purity.1-phenylisoquinoline was prepared by N-sulfonyl P-S three-step reaction using phenylethylamine and benzaldehyde as raw materials and the purity of the product reaches 98.5%.

关 键 词：磷光染料 异喹啉 1-苯基异喹啉 

分 类 号：TQ31[化学工程—高聚物工业]