气体水合物添加剂研究进展  

Research progress of gas hydrate additives

作　　者：敬加强[1,2] 郑天伦 杨航 曾霜 郭新根 JING Jiaqiang;ZHENG Tianlun;YANG Hang;ZENG Shuang;GUO Xin’gen(College of Petroleum&Gas Engineering,Southwest Petroleum University,Chengdu 610500,Sichuan,China;Oil and Gas Fire Protection Key Laboratory of Sichuan Province,Southwest Petroleum University,Chengdu 610500,Sichuan,China;Sichuan Northeast Gas Mine,PetroChina Southwest Oil and Gas Field Company,Dazhou 635000,Sichuan,China)

机构地区：[1]西南石油大学石油与天然气工程学院,四川成都610500 [2]西南石油大学油气消防四川省重点实验室,四川成都610500 [3]中国石油西南油气田公司川东北气矿,四川达州635000

出　　处：《天然气化工—C1化学与化工》2022年第6期22-32,共11页Natural Gas Chemical Industry

基　　金：国家自然科学基金(U19B2012)。

摘　　要：水合物添加剂是促进水合物技术大规模工业化应用的潜在选择,也是油气混输管道流动安全的保障介质,因而受到国内外研究者的广泛关注。为此,从水合物添加剂的类型、影响机理和性能评价方法出发,对最新研究进展进行了详细梳理。分析发现,低剂量绿色环保型材料是水合物添加剂的潜在发展方向;单一试剂作用机理基本明确,包括吸附和扰乱抑制机理,降低表面张力、形成临界胶束和毛细管效应促进机理,而针对不同类型添加剂的耦合作用机理尚需进一步研究。未来,应结合多种评价方法,从多角度验证并揭示水合物添加剂的作用效果和机理。Hydrate additive is not only a potential choice to promote large-scale industrial application of hydrate technology,but also a medium to guarantee the flow safety of oil-gas mixed transportation pipeline,so it has attracted extensive attention from researchers at home and abroad.Therefore,the latest research progress of hydrate additives was reviewed in detail from the types,influencing mechanisms and performance evaluation methods of hydrate additives.It is found that low dosage green material is the potential development direction of hydrate additive.The mechanism of single reagent is basically clear,including adsorption and disturbance for inhibition mechanism,reduction of surface tension,formation of critical micelle and capillary effect for promotion mechanism,but the coupling mechanism of different additives needs to be further studied.In the future,multiple evaluation methods should be combined to verify and reveal the effect and mechanism of hydrate additives from multiple perspectives.

关 键 词：水合物抑制剂 水合物促进剂 绿色添加剂 作用机理 评价方法 

分 类 号：TE883[石油与天然气工程—油气储运工程]