热聚石油树脂的高效合成  

Efficient synthesis of thermopolypetroleum resin

作　　者：杨莹娟 刘一豪 辛宜镡 马庭洲 伍家卫 周艳青 Yang Yingjuan;Liu Yihao;Xin Yixin;Ma Tingzhou;Wu Jiawei;Zhou Yanqing(Lanzhou Petrochemical Vocational and Technical University,Gansu Lanzhou 730060;不详)

机构地区：[1]兰州石化职业技术大学,甘肃兰州730060 [2]兰州拓能石化科技有限公司,甘肃兰州730060

出　　处：《石化技术》2022年第11期32-34,共3页Petrochemical Industry Technology

基　　金：2020年甘肃省高等学校产业支撑计划项目(2020C-33);2019年甘肃省科技重点研发计划项目(19YF3GA002);2017年甘肃省科技重点研发计划项目(17YF1GA028)。

摘　　要：为了降低热聚石油树脂的色号及提高生产效率,本文以C_(5)馏分、双环戊二烯(DCPD)和C_(9)馏分为原料,采用两段热聚合成法进行共聚反应制备C_(5)/DCPD/C_(9)共聚石油树脂。首先以C_(5)馏分为原料,在温度240℃、压力5.5MPa的条件下,热聚合反应6h,得到碳五低聚物,然后再将碳五低聚物、双环戊二烯(DCPD)、C_(9)馏分三者的混合物,在压力0.55-0.70MPa、温度为260℃的条件下,反应3-7小时,得到色号为4.0-5.0的浅色石油树脂。同时确定了在260°C反应4小时为最佳反应时间,所得石油树脂的软化点、色度、酸值、灰分等主要性能指标均达到优级品国家标准。In order to reduce the color number and improve the production efficiency of the thermopolymerized petroleum resin,the C_(5),DCPD,C_(9) copolymer was prepared by two-stage thermopolymerization with C_(5) fraction,DCPD and C_(9) fraction as raw materials.The C_(5) oligomer was prepared by thermal polymerization of C_(5) fraction at 240℃and 5.5 MPa pressure for 6 h,then the mixture of C_(5) oligomer,DCPD and C_(9) fraction was prepared,under the condition of pressure 0.55-0.70MPa and temperature 260℃,the light-colored petroleum resin with color number 4.0-5.0 was obtained by reaction for 3-7 hours.At the same time,the optimum reaction time was determined to be 4 hours at 260℃.The softening point,Chroma,acid value and ash content of the obtained petroleum resin were all up to the national standard of high-grade products.

关 键 词：C_(5)馏分 DCPD C_(9)馏分 热聚合成 C_(5)/DCPD/C_(9)共聚石油树脂 

分 类 号：TQ326.82[化学工程—合成树脂塑料工业]