金属有机骨架材料在含能领域中的应用研究  

Research on the Application of Metal-Organic Framework Materials in the Field of Energy

作　　者：王爽 杨利[1] 佟文超[1] 闫振展 韩纪旻 WANG Shuang;YANG Li;TONG Wen-chao;YAN Zhen-zhan;HAN Ji-min(State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,Beijing,100081)

机构地区：[1]北京理工大学爆炸科学与技术国家重点实验室,北京100081

出　　处：《火工品》2022年第6期1-8,共8页Initiators & Pyrotechnics

基　　金：国家自然科学基金(No.12102051)。

摘　　要：综述了近几年来金属有机骨架(Metal-Organic Framework,MOF)材料在含能领域中的应用研究进展,基于含能MOF配合物的构建方法及结构特点,阐述了以MOF中的金属元素为金属源在含能材料制备中的应用;概述了应用MOF的结构特点可用于爆炸物检测,也可作为氧化剂或燃烧催化剂添加于固体推进剂中。最后总结目前MOF在含能领域中的应用优势,指明了目前MOF在应用中存在的一些问题,并给出相应的意见。In this paper,the application research progress of metal-organic framework(MOF)materials in energetic materials in recent years was reviewed,based on the construction method and structure characters of MOF complexs,the metal elements in the MOF structure used as metal sources to prepare other energetic materials was expounded.The use of MOF in explosives detection and their applications as oxidants and combustion catalysts in solid propellants were also outlined.Finally,the application advantages of the current MOF structure in energetic materials were summarized,and some problems existing in the application of MOF in the energetic field were also pointed out,and corresponding opinions were given.

关 键 词：金属有机骨架 含能配位化合物 爆炸物检测 固体推进剂 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] TQ560.5[化学工程—炸药化工]