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作 者:曾丽瑶 胡恩源 王晓强 张钰豪 郭艳涛 Zeng Liyao;Hu Enyuan;Wang Xiaoqiang;Zhang Yuhao;Guo Yantao(Sinopec Petroleim Engineering Zhongyuan Corporation Natural Gas Technology Center,Zhengzhou 451000,Henan,China;Qingdao University of Science and Technology,Qingdao 266000,Shandong,China;Puyang Xinxing Clean Energy Co,,Ltd,,Puyang 457000,Henan,China;Sinopec Tianjin LNG Co.,Ltd.9Tianjin 300000,China)
机构地区:[1]中石化中原石油工程设计有限公司天然气技术中心,河南郑州451000 [2]青岛科技大学,山东青岛266000 [3]濮阳市新星清洁能源有限公司,河南濮阳457000 [4]中石化天津液化天然气有限责任公司,天津300000
出 处:《四川化工》2022年第6期30-33,共4页Sichuan Chemical Industry
基 金:中石化石油工程公司课题—地下煤合成气地面处理关键技术研究(SG21-48J)。
摘 要:地下煤蕴含的资源量十分巨大,地下煤合成气中CO_(2)含量比常规天然中的CO_(2)含量高,传统MDEA脱碳工艺无法较好地使地下煤合成气中的CO_(2)达到天然气净化指标要求。且传统的脱碳工艺再生能耗高,需要大量燃料气为脱碳再生系统提供能量。通过配方溶液筛选、工艺流程优化、关键参数研究等方法开展研究。结果表明,PZ+MDEA配方可明显提高CO_(2)吸收效率,超高CO_(2)含量合成气脱碳优化工艺可实现地下煤合成气脱碳工艺能耗同比下降55%。The underground coal contains a huge amount of resources.The CO_(2) content in the underground coal synthesis gas is higher than that in the conventional natural gas.The traditional MDEA decarburization process can not make the CO_(2)in the underground coal synthesis gas meet the requirements of natural gas purification.In addition,the traditional decarburization process requires a large amount of fuel gas to provide energy for the decarburization regeneration system.The research was carried out by means of formula solution screening,process optimization,key parameters research,etc.The results show that.The PZ+MDEA formula can significantly improve the CO_(2)absorption efficiency,and the optimized process for decarburization of synthetic gas with ultra-high CO_(2)content can realize a 55% year-on-year decrease in energy consumption of the process for decarburization of underground coal synthetic gas.
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