铜基卤化物钙钛矿制备方法及其应用研究进展  

Progress on the Preparation of Copper-based Halide and Their Applications

作　　者：董高磊 李梓榕 周倩倩 杨波波 梅时良 张璐 李威晨 钱麒 邹军 杨雪舟 DONG Gaolei;LI Zirong;ZHOU Qianqian;YANG Bobo;MEI Shiliang;ZHANG Lu;LI Weichen;QIAN Qi;ZOU Jun;YANG Xuezhou(School of Science,Shanghai Institude of Technology,Shanghai 201418,China;School of Information Science and Technology,Fudan University,Shanghai 200433,China;Huichuang Technology(Taizhou)Company Limited,Taizhou 318000,China;Zhejiang Anbei New Material Company Limited,Huzhou 313000,China;Jiangsu Pairui Electronics Company Limited,Nantong 226000,China;Tianchang Fuan Electronics Company Limited,Tianchang 239300,China;Ningbo Longer Lighting Company Limited.,Ningbo 315301,China)

机构地区：[1]上海应用技术大学理学院,上海201418 [2]复旦大学信息科学与工程学院,上海200433 [3]惠创科技(台州)有限公司,浙江台州318000 [4]浙江安贝新材料股份有限公司,浙江湖州313000 [5]江苏派锐电子有限公司,江苏南通226000 [6]天长市富安电子有限公司,安徽天长239300 [7]宁波朗格照明电器有限公司,浙江宁波315301

出　　处：《照明工程学报》2022年第6期61-75,共15页China Illuminating Engineering Journal

基　　金：国家重点研发计划“新型高性能稀土激光荧光材料的研制与应用”(2021YFB3501700);上海市2022年度“科技创新行动计划”农业科技领域项目“人工光型植物育苗工厂光源及光环境控制系统研究”(22N21900400);国家自然科学基金青年科学基金项目“胶体钙钛矿量子点电荷分离与自旋相干动力学”(12104311)。

摘　　要：无铅金属卤化物钙钛矿材料具有优异的发光性能、无毒性以及卓越的环境稳定性,成为下一代发光半导体的候选材料之一;其中,作为金属卤化物中的佼佼者,铜基卤化物因其低维结构和自陷激子(STE)发光特性而备受关注。相比于原有的三维铅基卤化物,具有STE发光特性的低维铜基卤化物拥有高量子效率的宽带发射,在复杂环境下稳定性高。本文综述了铜基卤化物钙钛矿材料和薄膜制备方法、光致发光特性以及应用前景,为铜基卤化物钙钛矿的研究发展提供参考。Lead-free metal halide perovskite materials have excellent luminescent properties,non-toxicity,and excellent environmental stability,and have become one of the candidate materials for the next generation of light-emitting semiconductors;among them,as the leader in metal halides,copper-based halide Materials have attracted much attention due to their low-dimensional structure and self-trapped exciton(STE)luminescence properties.Compared with the original three-dimensional lead-based halides,the low-dimensional copper-based halides with STE luminescence properties possess broadband emission with high quantum efficiency and high stability in complex environments.This paper reviews the preparation methods,photoluminescence properties and application prospects of copper-based halide perovskites materials and thin films,and provides a reference for the research and development of copper-based halide perovskites.

关 键 词：无铅 铜基卤化物钙钛矿 自陷激子 光电应用 

分 类 号：TN304.0[电子电信—物理电子学]