Piers硼烷的应用研究进展  

Research Progress of Piers′Borane

作　　者：谭敬杰 罗永安 吴翊乐 赵玉芬 TAN Jing-jie;LUO Yong-an;WU Yi-le;ZHAO Yu-fen(Institute of Drug Discovery Technology,Qian Xuesen Collaborative Research Center of Astrochemistry and Space Life Sciences,Ningbo University,Ningbo 315211,China;College of Chemistry and Chemical Engineering,Key Laboratory for Chemical Boology of Fujian Province,Xiamen University,Xiamen 361005,China)

机构地区：[1]宁波大学新药技术研究院天体化学与空间生命-钱学森空间科学协同研究中心,浙江宁波315211 [2]厦门大学化学化工学院福建省化学生物学重点实验室,福建厦门361005

出　　处：《化学试剂》2023年第1期1-11,共11页Chemical Reagents

基　　金：宁波市自然科学基金项目(202003N4094)。

摘　　要：基于主族元素的化学试剂和催化剂是当前研究的热点之一。HB(C_(6)F_(5))_(2)具有强路易斯酸性的硼中心,因此在小分子活化中具有特殊地位,可以活化包括一氧化碳在内的多种惰性小分子和化学键。同时,由于HB(C_(6)F_(5))_(2)具有可衍生化的硼氢键,因此也被用于构建含硼催化剂以及受阻路易斯酸碱对。经过多年的发展和使用,HB(C_(6)F_(5))_(2)被广泛应用于合成化学,并且以其发现者命名为Piers′Borane即Piers硼烷。综述了Piers硼烷近年来的应用进展,旨在为硼化合物在有机催化和小分子活化等领域的研究提供参考。Main group compounds play important roles in the modern chemistry including catalysis and small molecule activation.The strong Lewis acid HB(C_(6)F_(5))_(2),known as Piers′borane,can activate inert gas molecules such as carbon monoxide and nitrogen monoxide.Meanwhile,the B-H moiety is highly reactive and good for the introduction of a B(C_(6)F_(5))_(2) moiety into variety unsaturated compounds via hydroboration.Thus,a series of boron-containing chiral catalysts and frustrated Lewis pairs have been synthesized from HB(C_(6)F_(5))_(2).In this review,the use of Piers′borane in organic catalysis and small molecule activation was discussed.

关 键 词：路易斯酸 有机硼化合物 有机催化 小分子活化 受阻路易斯酸碱对 

分 类 号：O65[理学—分析化学]