二甲胺离子在钙钛矿太阳能电池及光电器件中的研究进展  

Research Progress of Dimethylamine Cation in Perovskite Solar Cells and Photoelectric Devices

作　　者：张左林 王成麟 陈聪 宋宏伟[2] ZHANG Zuolin;WANG Chenglin;CHEN Cong;SONG Hongwei(School of Material Science and Engineering,Hebei University of Technology,Tianjin 300130,China;State Key Laboratory of Integrated Optoelectronics College of Electronic Science and Engineering,Jilin University,Changchun 130012,China)

机构地区：[1]河北工业大学材料科学与工程学院,天津300130 [2]吉林大学电子科学与工程学院集成光电子学国家重点联合实验室,长春130012

出　　处：《材料导报》2022年第S02期1-8,共8页Materials Reports

基　　金：国家自然科学基金(62004058);河北省自然科学基金(F20202022)。

摘　　要：近年来,利用二甲胺(DMA)阳离子来改善钙钛矿太阳能电池(PSCs)及光电器件的性能引起了学者们的广泛关注。在钙钛矿前驱体溶液中添加半径较大的A位阳离子DMA,已被证明可以提高卤化物PSCs及光电器件的性能和长期运行稳定性。为了更好地了解这些改进的起源,本文综述了在钙钛矿前驱体溶液中添加DMA后,甲胺(MA)、甲脒(FA)、Cs、Pb和混合卤化物钙钛矿的薄膜结构、组成和光学性质的变化,并且对DMA离子在改善各种类型的PSCs和光电器件性能的作用进行了梳理,以期能够为将来的研究提供一些指导建议。In recent years,using dimethylamine cations(DMA)to improve the performance of perovskite solar cells(PSCs)and photoelectric devices has attracted widespread attention.The addition of DMA,an A-site cation with a larger radius,to the perovskite precursor solution has been proved to be able to improve the performance and long-term operational stability of halide PSCs and photoelectric devices.To better understand the origin of these improvements,this paper reviews the changes in film structure,composition and optical properties of methylamine(MA)formamidine(FA),Cs,Pb and mixed halide perovskite after the addition of DMA to the perovskite growth solution.And the role of DMA ions in improving the performance of various types of PSCs and photoelectric devices is sorted out.It is hoped that this review can provide some guiding suggestions for future research.

关 键 词：PSCs 光电器件 DMA 稳定性 带隙 

分 类 号：TM914[电气工程—电力电子与电力传动]