Rational Preparation of Atomically Precise Non-Alkyl Tin-Oxo Clusters with Theoretical to Experimental Insights into Electrocatalytic CO_(2)Reduction Applications  

作　　者：Di Wang Zhe-Ning Chen Qing-Rong Ding Cheng-Cheng Feng San-Tai Wang Wei Zhuang Lei Zhang 

机构地区：[1]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002 [2]University of Chinese Academy of Sciences,Beijing 100049

出　　处：《CCS Chemistry》2021年第10期2607-2616,共10页中国化学会会刊（英文）

基　　金：supported by the National Natural Science Foundation of China(nos.91961108,21922111,and 21973094);the National Key Research and Development Program of China(no.2017YFA0206801);the Strategic Priority Research Program of the Chinese Academy of Sciences(no.XDB20000000);the Natural Science Foundation of Fujian Province(no.2019J01131).

摘　　要：Tin oxides(SnO_(2))have been widely utilized in electronics,nanolithography,and catalysis.As the atomically precise models of SnO_(2),tin-oxo clusters(TOCs)not only provide opportunities for mechanism studies,but they also extend potential applications through structural modulation.However,to date,most of the reported TOCs belong to alkyl organotin complexes,which are usually toxic to the human body and the active sites are difficult to expose for catalysis.

关 键 词：cluster compounds tin oxides atomic structure green synthesis electrocatalytic CO_(2)red uction 

分 类 号：O62[理学—有机化学]