A review on the high energy oxidizer ammonium dinitramide:Its synthesis,thermal decomposition,hygroscopicity,and application in energetic materials  

作　　者：Fu-yao Chen Chun-lei Xuan Qiang-qiang Lu Lei Xiao Jun-qing Yang Yu-bing Hu Guang-Pu Zhang Ying-lei Wang Feng-qi Zhao Ga-zi Hao Wei Jiang 

机构地区：[1]National Special Superfine Powder Engineering Technology Research Center,Nanjing University of Science and Technology,Nanjing,China [2]Xi'an Modern Chemistry Research Institute,Xi'an,China

出　　处：《Defence Technology（防务技术）》2023年第1期163-195,共33页Defence Technology

基　　金：financially supported by the National Natural Science Foundation of China (Project No. 21805139, 12102194, 22005144 and 22005145);the Joint Funds of the National Natural Science Foundation of China (No. U2141202);Natural Science Foundation of Jiangsu Province (No. BK20200471);the Fundamental Research Funds for the Central Universities (No. 30920041106, 30921011203)

摘　　要：Ammonium dinitramide(ADN)is considered as a potential substitute for ammonium perchlorate in energetic materials due to its high density,positive oxygen balance,and halogen-free characteristics.However,its application has been severely limited because of its strong hygroscopicity,difficult storage,and incompatibility with isocyanate curing agents.In order to better bloom the advantages of the highly energetic and environment-friendly ADN in the fields of energetic materials,an in-depth analysis of the current situation and discussion of key research points are particularly important.In this paper,a detailed overview on the synthesis,thermal decomposition,hygroscopic mechanism,and antihygroscopicity of ADN has been discussed,its application in powdes and explosives are also presented,and its future research directions are proposed.

关 键 词：Ammonium dinitramide High energy oxidizer SYNTHESIS PROPERTIES APPLICATIONS 

分 类 号：TQ560.1[化学工程—炸药化工]