聚集诱导发光型氟硼二吡咯类染料研究进展  

Progress of BODIPY dyes with aggregation-induced emission

作　　者：卫婷 孙磊[1] 徐海军[1] 刘志鹏 沈珍[2] Ting Wei;Lei Sun;Haijun Xu;Zhipeng Liu;Zhen Shen(Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,Nanjing Forestry University,Nanjing 210037,China;State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China)

机构地区：[1]南京林业大学林业资源高效加工利用协同创新中心,南京210037 [2]配位化学国家重点实验室,南京大学化学化工学院,南京210023

出　　处：《中国科学：化学》2022年第12期2168-2182,共15页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:21971115)资助项目。

摘　　要：随着有机光电材料和生物成像技术的发展,研发具有聚集诱导发光(AIE)性能的有机发光材料逐渐成为材料科学研究的热点.氟硼二吡咯染料(BODIPY)因其优秀的发光性能已经成为AIE材料的研究对象之一.本文综述了近年来AIE型BODIPY的设计与合成、AIE性质的机理研究及其在荧光成像、气体传感、光动力诊疗和机械力致荧光变色材料等领域的应用.本文旨在探索AIE型BODIPY荧光材料的构效关系,通过分类、分析和总结,为BODIPY类聚集态发光材料的设计合成及其潜在应用的探索提供研究思路.With the development of organic optoelectronic materials and bioimaging technology,the investigation of organic light-emitting materials with aggregation-induced emission(AIE)properties has gradually become a hot spot in material science field.The fluoroborondipyrromethenes(BODIPY)dyes have become one of the research objects of AIE materials due to their excellent luminescence properties.This paper reviews the recent advances in the design and synthesis of AIE-type BODIPY derivatives,the mechanism of AIE properties and their promising applications in fluorescence imaging,gas sensing,photodynamic therapy,and mechanofluorochromic materials.It aims to explore the structure-activity relationship of AIE-type BODIPY fluorescent molecules,and provides ideas for the further design,synthesis and potential applications of BODIPY-type aggregated luminescent materials through classification,analysis and summary.

关 键 词：BODIPY 聚集诱导发光 荧光 生物成像 传感器 

分 类 号：TB34[一般工业技术—材料科学与工程]