Kinetics study of the N-formylation of aniline with DMF catalyzed by temperature-controlled Brùnsted ionic liquids  

作　　者：Yipeng Zheng Zhennan Cao Zheng Zhou Gaodong Yang Zhibing Zhang 

机构地区：[1]School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China

出　　处：《Chinese Journal of Chemical Engineering》2022年第12期154-160,共7页中国化学工程学报（英文版）

基　　金：financial support of National Natural Science Foundation of China(21776122);the Fundamental Research Funds for the Central Universities。

摘　　要：A series of SO_(3)-functional Br?nsted acidic ionic liquids(SBAILs)were prepared to catalyze the Nformylation of aniline with DMF.The reaction conditions such as ionic liquid type,reaction temperature.catalyst loading and molar ratio of reactants were investigated.To the best of our knowledge,kinetic model for the N-formylation of aniline with DMF using SBAIL was firstly built and simulated.The studies on the reaction order of the reaction were evaluated by initial concentration method,and the kinetic parameters such as reaction rate constant and activation energy were proposed and used to explain the catalytic activities of the SBAILs catalysts.Accordingly,the recycling experiments showed that the SBAIL[Bsmim][HSO_(4)]can be easily recovered and reused with stable activity.Further,the temperature-controlled study emphasized that the ionic liquid was easy to be separated and environmentally friendly.

关 键 词：N-formylation of aniline Ionic liquid Temperature-controlled system Kinetic 

分 类 号：O621.251[理学—有机化学]