新型超疏水苯并噁嗪树脂的合成与性能表征  

Synthesis and Characterization of Novel Superhydrophobic Benzoxazine Resin

作　　者：王钊 邹其超[2] WANG Zhao;ZOU Qi-chao(Wuhan Business University,Wuhan 430056;Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry,Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules,College of Chemistry and Chemical Engineering,Hubei University,Wuhan 430062)

机构地区：[1]武汉商学院,武汉430056 [2]有机化工新材料省部共建协同创新中心,功能材料绿色制备与应用教育部重点实验室,湖北大学化学化工学院,武汉430062

出　　处：《胶体与聚合物》2022年第4期186-189,共4页Chinese Journal of Colloid & Polymer

基　　金：武汉市科技局知识创新专项--基础研究项目(2022010801010425)。

摘　　要：本文采用壬基酚、长链脂肪胺与多聚甲醛通过无溶剂法合成系列的双长链苯并噁嗪树脂。并采用FT-IR、NMR、DSC、TG以及接触角测定等分析技术对聚合物的结构、聚合过程、热性能以及表面性能进行了表征。结果表明:随着聚合物中烷烃链增长,玻璃化温度越低且疏水性能越好。In this paper,a series of double long chain benzoxazine resins were synthesized by solvent-free method using nonylphenol,long-chain fatty amine and paraformaldehyde.The structure,polymerization process,thermal properties and surface properties of the polymer were characterized by FT-IR,NMR,DSC,TG and contact angle measurement.The results show that:with the increase of alkyl chain in the polymer,the glass transition temperature decreases and the hydrophobicity is enhanced.

关 键 词：疏水性 玻璃化温度 苯并噁嗪树脂 

分 类 号：O631[理学—高分子化学]