离聚物AClyn对扩链改性PET流变和结晶性能的影响  

Effects of ionomer AClyn on the rheological and crystalline properties of chain-extended modified PET

作　　者：聂鑫 郑家欣 信春玲[1,2] 何亚东[1,2] NIE Xin;ZHENG JiaXin;XIN ChunLing;HE YaDong(College of Mechanical and Electrical Engineering;Polymer Processing Equipment Engineering Research Center,Ministry of Education,Beijing University of Chemical Technology,Beijing 100029,China)

机构地区：[1]北京化工大学机电工程学院,北京100029 [2]北京化工大学教育部高分子材料加工装备工程研究中心,北京100029

出　　处：《北京化工大学学报（自然科学版）》2022年第6期32-39,共8页Journal of Beijing University of Chemical Technology(Natural Science Edition)

摘　　要：采用高分子钠盐类离聚物AClyn作为成核剂对均苯四甲酸二酐(PMDA)扩链增黏的聚对苯二甲酸乙二醇酯(PET)进行改性;研究了AClyn对PET/PMDA扩链体系熔体的黏弹性、分子链支化程度及结晶行为的影响;采用偏光显微镜(POM)观察改性PET的晶体形态,并采用X射线衍射仪(XRD)分析了改性PET的晶体构型,计算出各典型晶面的晶粒尺寸。结果表明:与未添加AClyn的PET/PMDA体系相比,添加0.2%~1.0%(质量分数)AClyn可以加快PET/PMDA体系的扩链反应速率,增大PET熔体的黏弹性,提高PET的分子链支化程度;AClyn对PET具有一定的降黏增塑作用,并且AClyn含量越高,增塑作用越大;AClyn添加量从0增大到1.0%时,改性PET的结晶温度和结晶度在总体上呈现出先减小后增大的变化趋势;AClyn作为异相成核剂可以促进PET结晶,加快结晶速率;相较于未添加AClyn的PET/PMDA体系,添加0.5%AClyn可以显著细化PET晶粒,减小晶粒尺寸。Polyethylene terephthalate(PET) with chain extension and viscosity enhancement by pyromellitic dianhydride(PMDA) was modified using the polymer sodium salt ionomer AClyn as a nucleating agent. The effects of AClyn on the viscoelasticity, molecular chain branching degree and the crystallization behavior of the PET/PMDA chain extension system were studied. The crystal morphology of modified PET was observed by polarizing microscopy(POM). The crystal structure of the modified PET was analyzed by X-ray diffraction(XRD), and the grain size on each typical crystal plane was calculated. The results showed that compared with the PET/PMDA system without AClyn, the addition of 0.2%-1.0% AClyn accelerated the chain extension reaction rate of the PET/PMDA system, increased the viscoelasticity of the PET melt and improved the molecular chain branching degree of PET. AClyn has a certain viscosity-reducing and plasticizing effect on PET, and the higher the content of AClyn, the greater the plasticizing effect. When the AClyn content was increased from 0 to 1.0%, the crystallization temperature and crystallinity of the modified PET initially decreased and then increased. The use of AClyn as a heterogeneous nucleating agent promotes PET crystallization and accelerates the crystallization rate. Compared with the PET/PMDA system without AClyn, adding 0.5% AClyn significantly alters the PET grains and reduces the grain size.

关 键 词：离聚物AClyn PET/PMDA扩链体系 流变性能 结晶行为 

分 类 号：TQ323.4[化学工程—合成树脂塑料工业]