Metal-Backboned Polymer:Conception,Design and Synthesis  

作　　者：Kai-Wen Zeng Hui-Sheng Peng 

机构地区：[1]State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science,Fudan University,Shanghai,200438,China

出　　处：《Chinese Journal of Polymer Science》2023年第1期3-6,共4页高分子科学（英文版）

基　　金：the National Natural Science Foundation of China(No.22105045);The Science and Technology Commission of Shanghai Municipality(Nos.20JC1414902 and 21511104900);Shanghai Municipal Education Commission(2017-01-07-00-07-E00062)。

摘　　要：The backbones of polymers are generally composed of non-metal elements such as C,N,O and Si.Here we propose and synthesize a new class of polymers whose backbones are completely made from metal atoms connected by chemical bonds,and they are thus named metal-backboned polymers.As a demonstration,nickel is selected as the metal to construct the nickel-backboned polymers with varied lengths,which are verified by mass spectrometry and studied by ultraviolet-visible spectroscopy.These metal-bonded polymers open up a new avenue to develop functional polymers in the future.

关 键 词：Metal-backboned NICKEL Functional POLYMER 

分 类 号：O631[理学—高分子化学]