生物质碳与MOF功能复合材料的应用研究新进展  

Recent Advances of Biomass Carbon and MOF Functional Composites and the Applications

作　　者：张泽俊 邵波 徐士官 蒋梦 罗书昌[1] 孙伟[1] ZHANG Zejun;SHAO Bo;XU Shiguan;JIANG Meng;LUO Shuchang;SUN Wei(Key Laboratory of Laser Technology and Optoelectronic Functional Materials of Hainan Province,Key Laboratory of Functional Materials and Photoelectrochemistry of Haikou,College of Chemistry and Chemical Engineering,Hainan Normal University,Haikou 571158,China;College of Chemistry and Chemical Engineering,Zhaotong University,Zhaotong 657000,China)

机构地区：[1]海南师范大学化学与化工学院/海南省激光技术与光电功能材料重点实验室/海口市功能材料与光电化学重点实验室,海南海口571158 [2]昭通学院化学化工学院,云南昭通657000

出　　处：《海南师范大学学报（自然科学版）》2022年第4期425-431,共7页Journal of Hainan Normal University（Natural Science）

基　　金：海南省重点研发计划项目(ZDYF2020204);国家自然科学基金项目(21964007);云南省教育厅科学研究基金项目(2019J1143)。

摘　　要：生物质碳具有独特的多孔结构,含有氧、氮和其他元素,具有较多的活性位点且价廉易得。而金属-有机骨架材料(MOF)也是一类多孔材料,具有丰富多样的形貌、高比表面积、化学可调控性和结构稳定性。通过原位生长工艺和煅烧处理,结合水热反应,可制备生物质碳与MOF功能复合材料。生物质碳与MOF功能复合材料比单独的生物质碳或MOF具有更大的比表面积和更多的活性位点,表现出许多优异的特性。本文重点介绍生物质碳与MOF复合材料在吸附剂、催化剂、电化学传感器、超级电容器、吸波材料和太阳能蒸发器等领域的最新应用研究进展,同时对该类复合材料未来的发展前景进行了展望。Biomass carbon has a unique porous structure,containing oxygen,nitrogen and other elements,with more active sites and low cost.Metal-organic frameworks(MOF)is a class of porous materials with diverse morphology,large surface area,chemical tunability and structural stability.Biomass carbon and MOF composites can be prepared by in-situ growth process and calcination treatment combined with hydrothermal reaction.The biomass carbon and MOF composites have larger specific surface area and abundant active sites than biomass carbon or MOF,which have many excellent characteristics.This paper focuses on the novel application of biomass carbon and MOF composites in the fields of adsorbents,catalysts,electrochemical sensors,supercapacitors,solar evaporators and electromagnetic wave absorbing materials.At the same time,the development prospects of this kind of composites are expected.

关 键 词：生物质碳 MOF 复合材料 应用 

分 类 号：TB333[一般工业技术—材料科学与工程]