聚氧化乙烯絮凝微细粒高岭石强化赤铁矿反浮选脱硅机理研究  

Mechanism Study of Enhanced Hematite Reverse Flotation Desilication by Flocculation of Micro Fine Kaolinite with Polyoxyethylene Oxide

作　　者：王俪嬴 郝晓宇 姚金[1] 杨斌[1] WANG Li-ying;HAO Xiao-yu;YAO Jin;YANG Bin(School of Resources&Civil Engineering,Northeastern University,Shenyang 110819,China)

机构地区：[1]东北大学资源与土木工程学院,辽宁沈阳110819

出　　处：《东北大学学报（自然科学版）》2023年第1期110-116,共7页Journal of Northeastern University(Natural Science)

基　　金：国家自然科学基金面上资助项目(51974064,51874072);中央高校基本科研业务费专项资金资助项目(N2101025).

摘　　要：通过矿物浮选试验并结合激光粒度测试、扫描电镜(SEM)、矿物Zeta电位及XPS等检测方法对赤铁矿反浮选过程中聚氧化乙烯絮凝细粒高岭石的行为及机理进行了研究.矿物絮凝浮选试验表明:添加聚氧化乙烯可以提高高岭石的单矿物回收率和人工混合矿分离效率,促进赤铁矿和高岭石反浮选分离.激光粒度测试和扫描电镜检测结果表明:聚氧化乙烯不絮凝赤铁矿,但絮凝高岭石颗粒,使其表观粒径增大.Zeta电位测试和XPS分析表明:聚氧化乙烯在高岭石颗粒表面发生化学吸附,并使其Zeta电位正移.因此,开展聚氧化乙烯对硅酸盐矿物絮凝的研究对赤铁矿和高岭石反浮选分离具有意义.Mineral flotation test,combined with laser particle size test,scanning electron microscope(SEM),mineral surface potential and XPS(X-ray photoelectron spectroscopy)were used to study the behavior and mechanism of polyoxyethylene oxide(PEO)flocculation of fine kaolinite in the process of hematite reverse flotation.The flotation test showed that the addition of PEO improves the mineral recovery of kaolinite and the separation efficiency of artificial mixed ore,which is conducive to promoting the reverse flotation separation of hematite and kaolinite.The results of laser particle size test and SEM showed that PEO does not flocculate hematite,but flocculates kaolinite particles to increase their apparent particle size.Zeta-potential tests and XPS analysis indicated that chemical adsorption of PEO occurs on the surface of kaolinite particles,and its Zeta-potential is positively shifted.Therefore,PEO has certain guiding significance in the study of reverse flotation separation of hematite and kaolinite.

关 键 词：聚氧化乙烯 高岭石 赤铁矿 反浮选:絮凝 

分 类 号：TD923[矿业工程—选矿]