无卤阻燃聚酯复合材料研究进展  

Research progress in halogen-free flame-retardant polyester composites

作　　者：刘昊育 辛菲[1,2,3,4] 杜家盈 樊晓玲 LIU Haoyu;XIN Fei;DU Jiaying;FAN Xiaoling(School of Chemistry and Materials Engineering,Beijing Technology and Business University,Beijing 100048,China;Beijing Key Laboratory of Quality Evaluation Technology for Hygiene and Safety of Plastics,Beijing 100048,China;China Light Industry Engineering Technology Research Center of Advanced Flame Retardants,Beijing 100048,China;Petroleum and Chemical Industry Engineering Laboratory of Non-halogen Flame Retardants for Polymers,Beijing 100048,China)

机构地区：[1]北京工商大学化学与材料工程学院,北京100048 [2]北京市塑料卫生安全质量评价技术重点实验室,北京100048 [3]中国轻工业先进阻燃剂工程技术研究中心,北京100048 [4]石油和化学工业聚合物无卤阻燃剂工程实验室,北京100048

出　　处：《中国塑料》2023年第1期133-143,共11页China Plastics

基　　金：国家自然科学基金(52173213)。

摘　　要：综述了近5年来的无卤阻燃聚酯复合材料的研究进展。讨论了有机阻燃剂(如磷酸盐、磷酸酯等)、无机阻燃剂(如红磷、蒙脱土等)和有机无机配合阻燃体系(如氢氧化铝/聚磷酸铵/可膨胀石墨等)等几大类阻燃体系阻燃聚酯后复合材料的力学性能、热稳定性、相容性、抑烟性以及不同添加量下热释放速率的变化,并对高效、环境友好的无卤阻燃聚酯复合材料的前景进行了展望。This paper reviewed the research progress in the halogen-free flame-retardant polyester-based composites in recent five years. The variations of mechanical properties, thermal stability, compatibility, smoke suppression, and heat release rate of the composites were discussed after the flame-retardant modification was performed by using organic flame retardants like phosphate and phosphonate, inorganic flame retardants like red phosphorus and montmorillonite, and organic-inorganic flame-retardant systems like aluminum hydroxide/ammonium polyphosphate/expandable graphite composite system. The future development trend of halogen-free flame-retardant polyester composites with highly efficient and environmentally friendly characteristics was prospected.

关 键 词：聚酯复合材料 无卤阻燃 阻燃机理 综合性能 

分 类 号：TQ323.4[化学工程—合成树脂塑料工业]