Efficient Photocatalytic Reduction of CO_(2)Catalyzed by the Metal–Organic Framework MFM-300(Ga)  

作　　者：Tian Luo Zi Wang Xue Han Yinlin Chen Dinu Iuga Daniel Lee Bing An Shaojun Xu Xinchen Kang Floriana Tuna Eric JLMcInnes Lewis Hughes Ben FSpencer Martin Schröder Sihai Yang 

机构地区：[1]Department of Chemistry,University of Manchester,Manchester M139PL [2]Photon Science Institute(PSI),University of Manchester,Manchester M139PL [3]Department of Physics,University of Warwick,Coventry CV47AL [4]Department of Chemical Engineering and Analytical Science,University of Manchester,Manchester M139PL [5]Institute of Chemistry,Chinese Academy of Science,Beijing 100190 [6]Department of Earth and Environmental Sciences,University of Manchester,Manchester M139PL [7]Department of Materials,University of Manchester,Manchester M139PL

出　　处：《CCS Chemistry》2022年第8期2560-2569,共10页中国化学会会刊（英文）

基　　金：supported by EPSRC(EP/I011870,EP/V056409);the Royal Society and the University of Manchester with funding,and EPSRC for funding of the EPSRC National EPR Facility at the University of Manchester.This project has also received funding from the European Research Council under the European Union’s Horizon 2020 research and innovation programme(grant agreement No 742401,NANOCHEM).The UK High-Field Solid-State NMR Facility used in this research was funded by EPSRC and BBSRC(EP/T015063/1)as well as the University of Warwick including via partial funding through Birmingham Science City Advanced Materials Projects 1 and 2 supported by Advantage West Midlands and the European Regional Development Fund.

摘　　要：Photocatalytic reduction of CO_(2)to carbon fuels is an important target but highly challenging to achieve.Here,we report the efficient photoconversion of CO_(2)into formic acid over a Ga(Ⅲ)-based metal–organic framework(MOF)material using triethanolamine as the sacrificial agent.Under light irradiation and at room temperature,photoreduction of CO_(2) over MFM-300(Ga)yields formic acid with a selectivity of 100%.

关 键 词：MFM-300 metal–organic framework CO_(2)reduction PHOTOCATALYSIS host–guest interaction 

分 类 号：O64[理学—物理化学]