General and Efficient C–P Bond Formation by Quantum Dots and Visible Light  

作　　者：Rui-Nan Ci Cheng Huang Lei-Min Zhao Jia Qiao Bin Chen Ke Feng Chen-Ho Tung Li-Zhu Wu 

机构地区：[1]Key Laboratory of Photochemical Conversion and Optoelectronic Materials,Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100190 [2]School of Future Technology,University of Chinese Academy of Science,Beijing 100049

出　　处：《CCS Chemistry》2022年第9期2946-2952,共7页中国化学会会刊（英文）

基　　金：support from the National Natural Science Foundation of China(nos.22088102,21933007,and 22193013);the Ministry of Science and Technology of China(nos.2017YFA0206903,2021YFA1500102,and 2021YFA1500802);the Strategic Priority Research Program of the Chinese Academy of Science(no.XDB17000000);the Key Research Program of Frontier Sciences of the Chinese Academy of Science(no.QYZDY-SSW-JSC029).

摘　　要：The photocatalytic C–P bond formation reaction involving phosphoryl radicals provides a powerful strategy in phosphorus chemistry.However,the engagement of the phosphoryl radical-forming reaction without stoichiometric oxidants or radical initiators has proven difficult.

关 键 词：PHOTOCATALYSIS quantum dots C–P bond formation hydrophosphinylation of alkenes crosscoupling hydrogen evolution reaction 

分 类 号：O62[理学—有机化学]