Nickel-Catalyzed Regiodivergent Asymmetric Cycloadditions of α,β-Unsaturated Carbonyl Compounds  

作　　者：Shi Cao Ziqi Ye Yuehua Chen Yu-Mei Lin Jiahua Fang Yuejiao Wang Boxuan Yang Lei Gong 

机构地区：[1]Key Laboratory of Chemical Biology of Fujian Province,iChEM,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen,Fujian 361005

出　　处：《CCS Chemistry》2022年第9期3122-3133,共12页中国化学会会刊（英文）

基　　金：from the National Natural Science Foundation of China(grant nos.22071209 and 22071206);the National Youth Talent Support Program,the Natural Science Foundation of Fujian Province of China(grant no.2017J06006);the Fundamental Research Funds for the Central Universities(grant no.20720190048);Basic Disciplines Training Program for Top-notch Students of the Ministry of Education.

摘　　要：Regiodivergent asymmetric cycloadditions from the same set of starting materials offer interesting opportunities for rapid construction of optically active cyclic molecules with structural diversity.However,this remains a challenging task due to the difficulty of simultaneously controlling the regio-,diastereo-,and enantioselectivity in the ring formation processes.To address this long-standing problem.

关 键 词：CYCLOADDITION regiodivergent asymmetric photocatalysis visible light nickel 

分 类 号：O62[理学—有机化学]