Electrochemical Rhodium-Catalyzed Enantioselective C–H Annulation with Alkynes  

作　　者：Yuan-Qiong Huang Zhi-Jie Wu Li Zhu Qing Gu Xiaojie Lu Shu-Li You Tian-Sheng Mei 

机构地区：[1]State Key Laboratory of Organometallic Chemistry,Center for Excellence in Molecular Synthesis,Shanghai Institute of Organic Chemistry,University of Chinese Academy of Sciences,Chinese Academy of Sciences,Shanghai 200032 [2]State Key Laboratory of Drug Research,Shanghai Institute of Materia Medica,Chinese Academy of Sciences,Pudong,Shanghai 201203

出　　处：《CCS Chemistry》2022年第9期3181-3189,共9页中国化学会会刊（英文）

基　　金：grant fromNSFC(nos.21821002,21772222,and 91956112),CAS(no.XDB20000000);Science and Technology Commission of Shanghai Municipality(nos.18JC1415600 and 20JC1417100).

摘　　要：The synergistic use of transition metal catalysis and electrochemistry is an attractive strategy for oxidative site-selective C–H functionalization since the use of stoichiometric chemical oxidants can be avoided and novel reactivity can be achieved.However,metalcatalyzed electrochemical C–H functionalization is mainly limited to arene C(sp^(2))–Hfunctionalization,and enantioselective C–H functionalization is uncommon and remains challenging.

关 键 词：organic electrochemistry enantioselective C–H annulation rhodium catalysis chiral spiropyrazolones C–H functionalization 

分 类 号：O62[理学—有机化学]