Three-Component Asymmetric Polymerization toward Chiral Polymer  

作　　者：Ming Li Xuelun Duan Yu Jiang Xinhao Sun Xiang Xu Junnan He Yubin Zheng Wangze Song Nan Zheng 

机构地区：[1]State Key Laboratory of Fine Chemicals,School of Chemical Engineering,Dalian University of Technology,Dalian 116024

出　　处：《CCS Chemistry》2022年第10期3402-3415,共14页中国化学会会刊（英文）

基　　金：supported by the National Science Foundation of China(No.21978039);Special Funds of the Central Government Guiding Local Science and Technology Development(Nos.2021JH6/10500148 and 2021JH6/10500146);the Natural Science Foundation of Jiangsu Province(No.BK20211100);and the Fundamental Research Funds for the Central Universities(Nos.DUT20YG120 and DUT21YG133).

摘　　要：Chiral-polymers with metal-coordination ability showgreat potential formediating asymmetric reactions.However,the synthesis of structurally diverse chiral polymers remains a great challenge,especially doing so efficiently.Herein,four types of Cucatalyzed multicomponent asymmetric polymerizationswere developed using a flexible combination of OBoc-alkyne.

关 键 词：multicomponent polymerization asymmetric polymerization chiral polymer macromolecular catalyst aqueous CuAAC reaction 

分 类 号：O62[理学—有机化学]