长链烯烃氢甲酰化反应催化剂研究进展  

Research progress of catalysts for hydroformylation of long chain olefins

作　　者：燕子红 郑源松 蔡岩[2] 苗志伟[3] YAN Zihong;ZHENG Yuansong;CAI Yan;MIAO Zhiwei(College of Chemistry and Environmental Science,Kashgar University,Kashgar 844006,China;Tianjin International Joint Academy of Biomedicine,Tianjin 300457,China;College of Chemistry,State Key Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin 300071,China)

机构地区：[1]喀什大学化学与环境科学学院,新疆喀什844006 [2]天津国际生物医药联合研究院,天津300457 [3]南开大学化学学院元素有机化学国家重点实验室,天津300071

出　　处：《石油化工》2023年第1期116-123,共8页Petrochemical Technology

基　　金：国家自然科学基金项目(22071113);南开大学沧州渤海新区绿色化工研究院基金项目(NCC2020FH01)。

摘　　要：介绍了不同含膦配体改性的金属铑催化剂在长链烯烃氢甲酰化反应中的应用,综述了单齿膦配体、双齿膦配体和多齿膦配体的合成方法及其在长链烯烃氢甲酰化反应中的应用研究进展。分析了不同分子结构膦配体的电子效应和空间效应及其对烯烃氢甲酰化反应的影响,介绍了烯烃氢甲酰化反应金属催化剂的制备方法,并对未来长链烯烃氢甲酰化反应的发展方向进行了展望。This paper introduces the application of rhodium catalysts modified with different phosphorus containing ligands in hydroformylation of long-chain olefins. The preparation methods of monodentate phosphine ligands,bidentate phosphine ligands and polydentate phosphine ligands and their application in hydroformylation of long-chain olefins are reviewed. The electronic and steric effects of phosphorus ligands with different molecular structures and their effects on hydroformylation of olefins are analyzed. The preparation methods of metal catalysts for olefin hydroformylation are described,and the development trend of long chain olefin hydroformylation in the future is prospected.

关 键 词：长链烯烃 氢甲酰化反应 催化剂 膦配体 

分 类 号：TQ426[化学工程]