密实化方式对废弃聚酯纺织品的醇解及酯交换产物的影响  

Effects of densification methods on glycolysis and transesterification products of waste polyester textiles

作　　者：刘志阳 官军 顾日强 吕维扬 王秀华[1] 姚玉元[1,2] LIU Zhiyang;GUAN Jun;GU Riqiang;Lü Weiyang;WANG Xiuhua;YAO Yuyuan(National Engineering Lab for Textile Fiber Materials and Processing Technology,Zhejiang Sci-Tech University,Hangzhou 310018,China;Zhejiang Provincial Innovation Center of Advanced Textile Technology,Shaoxing 312000,China;Zhejiang Jiaren New Materials Co.,Ltd,Shaoxing 312000,China)

机构地区：[1]浙江理工大学纺织纤维材料与加工技术国家地方联合工程实验室,杭州310018 [2]浙江省现代纺织技术创新中心,浙江绍兴312000 [3]浙江佳人新材料有限公司,浙江绍兴312000

出　　处：《现代纺织技术》2023年第1期123-129,共7页Advanced Textile Technology

基　　金：浙江省“尖兵”“领雁”研发攻关计划项目(2022C01197)。

摘　　要：废弃聚酯纺织品的密实化方式是影响聚酯醇解、酯交换过程中反应效率及成本的关键因素。采用强力搅拌摩擦、高温熔融和螺杆加热挤出3种不同密实化方式将废弃聚酯纺织品制成泡料、熔融料和熔融挤出料,使用乙二醇解聚3种废弃聚酯原料,将醇解产物与甲醇通过酯交换反应制得再生对苯二甲酸二甲酯(DMT),研究不同密实化方式对废弃聚酯纺织品的醇解及酯交换产物的影响。结果表明:在相同醇解条件下,泡料、熔融料、熔融挤出料在120 min内分别达到了99.2%、99.0%和98.2%的最大解聚率以及69.7%、68.8%和65.2%的对苯二甲酸乙二醇酯(BHET)收率,醇解产物的主要成分为BHET及其二聚体,低聚物的含量随着解聚程度的增加而降低;3种醇解产物与甲醇在相同条件下进行酯交换反应,泡料、熔融料和熔融挤出料的DMT收率在2.5h内分别达到81.2%、76.8%和72.2%,3种酯交换产物经4次甲醇重结晶纯化后DMT的含量均高于99%,能够满足下游高性能再生聚酯产品的要求。研究结果为再生聚酯行业中选择适宜原料提供了有价值的参考。Polyester fiber,with excellent elasticity,wrinkle resistance and shape conformal property,is widely used in textile clothing,industrial packaging and other fields.As the amount of polyester fiber increases,the accumulation of waste polyester textiles also rises year by year,resulting in serious environmental pollution and resource waste problems.Waste polyester is depolymerized by chemical solvents to monomer as an effective raw material for the synthesis of high value-added recycled polyester materials,which is an effective way to achieve high-value recycling of the waste polyester textiles.Among the chemical methods,the glycolysis method not only has the advantages of mild reaction conditions and simple process,but also the ester exchange reaction between the alcoholysis product BHET and methanol can produce regenerated DMT comparable to primary petroleum-based materials,which is the most promising process route for the industrial preparation of the high-quality regenerated polyester materials.The densification methods of waste polyester textiles are a key factor affecting the efficiency and cost of the reaction during polyester alcoholysis and transesterification.However,most of the current glycolysis methods focus on the development of new and efficient depolymerization catalysts,and little research has been reported on the effect of different densification retreatment processes of raw materials on the alcoholysis products and the downstream regenerated DMT thereof.In order to find the most suitable dense raw material for industrial decomposing poly waste polyester textile and preparation of regenerated DMT,the foaming,melt materials and melt extrusion materials derived from waste polyester textiles were prepared by the three densification methods of strong friction stirring,high temperature melting and screw heated extrusion,and depolymerized by ethylene glycol.Then,the alcoholysis products were futher transesterified by methanol to prepare the regenerative dimethyl terephthalate.The effect of different dens

关 键 词：废弃聚酯 密实化 醇解 酯交换 再生DMT 

分 类 号：TQ342.21[化学工程—化纤工业]