Low-cost preferential different amine grafted silica spheres adsorbents for DAC CO_(2)removal  

作　　者：Salman Qadir Hongjiu Su Defu Li Yiming Gu Shengsheng Zhao Sheng Wang Shudong Wang 

机构地区：[1]Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China [2]University of Chinese Academy of Sciences,Beijing 100049,China

出　　处：《Journal of Energy Chemistry》2022年第12期494-503,I0013,共11页能源化学（英文版）

基　　金：funded by the National Science Foundation of China(U20A20132);the National Key Scientific Research Project(2016YFC0204302);the Dalian Institute of Chemical Physics(DICP I201937);the K.C.Wong Education Foundation。

摘　　要：DAC CO_(2)capture is gaining wide attention as one of the most difficult carbon approaches to tackle climate change.In this work,different pore-size silica spheres were grafted using different amine groups such as APTES,APTMS,and Diamine.Herein,all samples based on the wet and dry grafting method were used for CO_(2)adsorption isotherm at room temperature and pressure(298 K and 1 bar).The sample based on the wet grafting(Silica-APTES-W)sample shows the highest CO_(2)uptake 1.67 mmol/g.Also,the adsorption isotherm of the Silica-APTES-W sample was showed a high capacity of CO_(2)1.2 mmol/g at 25℃,which describes the strong physical interaction between CO_(2)and amine.The isosteric adsorption of Silica-APTES-W also confirmed that the physical adsorption was dominant because of low adsorption heat ranging from 23 to 37 k J/mol.Also,the fixed bed experiment was conducted with 2000 ppm CO_(2)that obtains the optimal working capacity 4.5 m L/g with the lowest regeneration temperature 90℃.It was shown that Silica-APTES-W sample was superior performance for DAC CO_(2)capture in practical applications.

关 键 词：CO_(2)capture Direct air capture Silica spheres APTES APTMS DIAMINE 

分 类 号：TQ424[化学工程] X701[环境科学与工程—环境工程]