楠竹活性炭同时对敌草隆和3,4-二氯苯胺吸附  

Simultaneous Adsorption of Diuron and 3,4-dichloroaniline from Water on Nanzhu Activated Carbon

作　　者：段珊珊 吴国勇 孙晓波 王小明 陈碧 DUAN Shan-shan;WU Guo-yong;SUN Xiao-bo;WANG Xiao-ming;CHEN Bi(College of Food and Biochemical Engineering,Guangxi Science and Technology Normal University,Guangxi Laibin 546119,China)

机构地区：[1]广西科技师范学院食品与生化工程学院,广西来宾546119

出　　处：《广州化工》2022年第23期88-92,101,共6页GuangZhou Chemical Industry

基　　金：广西糖资源工程技术研究中心培育建设(桂科AD16450040);广西高校制糖工程综合技术重点实验室培育建设(桂教科研[2016]6号);广西科技师范学院糖蔗资源绿色高效技术开发与应用青年科研创新团队(GXKS2020QNTD01);糖料蔗绿色高效生产技术重点实验室(GXKSKYPT2021006)。

摘　　要：以楠竹粉为原料,采用磷酸活化法制备楠竹活性炭,并研究其同时对水中敌草隆和3,4-二氯苯胺的吸附性能。借助傅立叶变换红外光谱、扫描电子显微镜、比表面积分析仪对样品进行形貌表征,发现其表面具有丰富的含氧官能团和发达的孔隙结构其比表面积为947.96 m^(2)/g。当楠竹活性炭添加量为4 mg时,对敌草隆和3,4-二氯苯胺的吸附量分别为70.66 mg/g和64.90 mg/g,其吸附机理类型均符合Freundlich模型与准二级动力学模型。The preparation of activated carbon(AC) from Nanzhu was studied by chemical activation with phosphoric acid, and then AC was used for the simultaneous adsorption of diuron and 3,4-dichloroaniline in water. It was characterized by SEM, FT-IR and BET. The results showed that AC possessed oxygen-containing functional groups and abundant pore structure, and its specific surface area 947.96 m^(2)/g. The activated carbon was added in an amount of 4 mg, and it showed an adsorption capacity of 70.66 mg/g and 64.90 mg/g for diuron and 3,4-dichloroaniline.The adsorption of diuron and 3,4-dichloroaniline fitted to the kinetics accords with the pseudo-second-order model and the Langmuir model.

关 键 词：楠竹活性炭 同时吸附 敌草隆 3 4-二氯苯胺 

分 类 号：X712[环境科学与工程—环境工程]