电、光和光电催化甘油选择性氧化合成二羟基丙酮的研究进展  

Recent advanceson selective electro-,photo-,and photoelectrocatalytic glycerol oxidation to dihydroxyacetone

作　　者：邬娇娇 徐向亚[1] 刘东兵[1] 邵芸[1] 刘红梅[1] Wu Jiaojiao;Xu Xiangya;Liu Dongbing;Shao Yun;Liu Hongmei(Sinopec Beijing Research Institute of Chemical Industry,Beijing 100013,China)

机构地区：[1]中国石化北京化工研究院,北京100013

出　　处：《工业催化》2023年第1期8-14,共7页Industrial Catalysis

基　　金：中国石油化工股份有限公司北京化工研究院院控项目(6-21ZS0224)。

摘　　要：甘油,作为生物柴油生产过程中的主要副产物,能够通过不同的催化过程转化为高附加值产品。由电、光和光电驱动的甘油选择性氧化合成被广泛应用于化妆品和医药等行业的二羟基丙酮(DHA)是很有前景的反应途径之一。对近年来在电、光和光电催化甘油选择性氧化合成DHA领域的研究进展进行综述,重点集中在高活性和高选择性催化剂的开发方面。同时对电、光和光电催化甘油选择性氧化合成DHA面临的挑战和发展前景进行展望。Glycerol,as the major byproduct in biodiesel production,can transform to value-added products via different catalytic processes.Selective electro-,photo-,and photoelectrocatalytic glycerol oxidation to dihydroxyacetone(DHA),which widely used in cosmetic,pharmaceutical industries,etc.is one of the most promising reaction pathways.This review describes the recent research developments in selective electro-,photo-,and photoelectrocatalytic glycerol oxidation to DHA and special emphasis is put on the design of high-activity and high-selectivity catalysts.Furthermore,the challenges and future prospects in selective electro-,photo-,and photoelectrocatalytic glycerol oxidation to DHA are overviewed.

关 键 词：精细化学工程 甘油 选择性催化氧化 二羟基丙酮(DHA) 

分 类 号：TQ426.6[化学工程] TQ645.5