Progress in quantitative research on the relationship between atmospheric oxidation and air quality  

作　　者：Yuesi Wang Xin Jin Zirui Liu Gehui Wang Guiqian Tang Keding Lu Bo Hu Shanshan Wang Guohui Li Xinqin An Chao Wang Qihou Hu Lingyan He Fenfen Zhang Yuanhang Zhang 

机构地区：[1]State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry(LAPC),Institute of Atmospheric Physics,Chinese Academy of Sciences,Beijing 100029,China [2]College of Earth and Planetary Sciences,University of Chinese Academy of Sciences,Beijing 100049,China 3 State Key Joint Laboratory or Environmental Simul [3]ation and Pollution Control,College of Environmental Sciences and Engineering,Peking University,Beijing 100871,China [4]State Key Joint Laboratory of Environmental Simulation and Pollution Control,School of Environment,Tsinghua University,Beijing 100084,China [5]Key Lab of Geophysical Information System of the Ministry of Education,School of Geographic Sciences,East China Normal University,Shanghai 200241,China [6]Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(LAP3),Department of Environmental Science and Engineering,Fudan University,Shanghai 201203,China [7]Key Lab of Aerosol Chemistry and Physics,State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,Chinese Academy of Sciences,Xi’an 710061,China [8]Institute of Atmospheric Composition and Environmental Meteorology,Chinese Academy of Meteorological Sciences,Beijing 100081,China [9]Key Lab of Environmental Optics and Technology,Anhui Institute of Optics and Fine Mechanics,Hefei Institutes of Physical Science,Chinese Academy of Sciences,Hefei 230031,China

出　　处：《Journal of Environmental Sciences》2023年第1期350-366,共17页环境科学学报（英文版）

基　　金：supported by the Ministry of Science and Technology of the People’s Republic of China(No.2017YFC0210000);the Young Talent Project of the Center for Excellence in Regional Atmospheric Environment,CAS(No.CERAE202002);the National Natural Science Foundation of China(No.41705110);Beijing Major Science and Technology Project(No.Z211100004321006)。

摘　　要：Atmospheric oxidizing capacity(AOC)is an essential driving force of troposphere chemistry and self-cleaning,but the definition of AOC and its quantitative representation remain uncertain.Driven by national demand for air pollution control in recent years,Chinese scholars have carried out studies on theories of atmospheric chemistry and have made considerable progress in AOC research.This paper will give a brief review of these developments.First,AOC indexes were established that represent apparent atmospheric oxidizing ability(AOIe)and potential atmospheric oxidizing ability(AOIp)based on aspects of macrothermodynamics and microdynamics,respectively.A closed study refined the quantitative contributions of heterogeneous chemistry to AOC in Beijing,and these AOC methods were further applied in Beijing-Tianjin-Hebei and key areas across the country.In addition,the detection of ground or vertical profiles for atmospheric OH·,HO_(2)·,NO_(3)·radicals and reservoir molecules can now be obtained with domestic instruments in diverse environments.Moreover,laboratory smoke chamber simulations revealed heterogeneous processes involving reactions of O_(3)and NO_(2),which are typical oxidants in the surface/interface atmosphere,and the evolutionary and budgetary implications of atmospheric oxidants reacting under multispecies,multiphase and multi-interface conditions were obtained.Finally,based on the GRAPES-CUACE adjoint model improved by Chinese scholars,simulations of key substances affecting atmospheric oxidation and secondary organic and inorganic aerosol formation have been optimized.Normalized numerical simulations of AOIe and AOIp were performed,and regional coordination of AOC was adjusted.An optimized plan for controlling O_(3)and PM2.5was analyzed by scenario simulation.

关 键 词：Atmospheric oxidizing capacity(AOC) Quantitative index Free radicals Observation and modeling Air quality 

分 类 号：X87[环境科学与工程—环境工程] X835