Recent advances in electrooxidative radical transformations of alkynes  

作　　者：Yan Zhang Zhenzhi Cai Svenja Warratz Chanchan Ma Lutz Ackermann 

机构地区：[1]Key Laboratory of the Ministry of Education for Advanced Catalysis Materials,Drug Discovery&Innovation Center,College ofChemistry and Life Sciences,Zhejiang Normal University,Jinhua 321000,China [2]Institut für Organische und Biomolekulare Chemie and Woehler Research Institute for Sustainable Chemistry(WISCh),Georg-August-Universität Göttingen,Germany

出　　处：《Science China Chemistry》2023年第3期703-724,共22页中国科学（化学英文版）

基　　金：supported by the Natural Science Foundation of Zhejiang Province(LY22B020001);the National Natural Science Foundation of China(21702188);the ERC Advanced Grant(101021358);the Gottfried-Wilhelm-Leibniz award to LA(DFG).

摘　　要：During the past few years,electrochemical oxidative reactions through radical intermediates have emerged as an environmentally-benign,powerful platform for the facile formation of C–E(E=C,N,S,Se,O and Hal)bonds through singleelectron-transfer(SET)processes at the electrodes.Functionalized unsaturated molecules and unusual structural motifs can,for instance,be directly constructed under exceedingly mild reaction conditions through initial radical attack onto alkynes.This minireview highlights the recent advances in electrooxidation in radical reactions until June 2022,with a particular focus on radical additions onto alkynes.

关 键 词：ELECTROSYNTHESIS ELECTROOXIDATION RADICALS ALKYNES ADDITIONS difunctionalization 

分 类 号：O62[理学—有机化学]