锯齿板状阴极电化学除垢工艺优化及机理研究  

Mechanism and process optimization of serrated plate cathode for electrochemical descaling

作　　者：黄亚鹏 赵世鑫 王立达[1] 刘贵昌[1] 贺永鹏 邓海涛 刘锦程 孙文[1] HUANG Ya-peng;ZHAO Shi-xin;WANG Li-da;LIU Gui-chang;HE Yong-peng;DENG Hai-tao;LIU Jin-cheng;SUN Wen(School of Chemical Engineering,Dalian University of Technology,Dalian 116024,China;Shandong Chambroad Holding Group Co.,Ltd.,Binzhou 256500,China)

机构地区：[1]大连理工大学化工学院,辽宁大连116024 [2]山东京博控股集团有限公司,山东滨州256500

出　　处：《现代化工》2023年第2期110-116,共7页Modern Chemical Industry

基　　金：国家自然科学基金项目(21978036)。

摘　　要：针对电化学除垢系统处理工业循环冷却水时能耗高的问题,采用锯齿板状阴极使系统能耗低至6.82 kW·h/(kg CaCO_(3))。实验和数值模拟结果表明,系统能耗降低是因为锯齿板状阴极的尖端区域水垢的沉积速率快、垢层与阴极结合力弱,使得垢层容易脱落;同时垢层覆盖锯齿状阴极尖端区域后,垢层沉积反应逐渐由尖端区域向平缓区域转移,大大延长了阴极失活时间,使得电化学除垢系统能耗降低。因此,通过尖端区域和平缓区域的协同作用,可以有效缓解阴极失活导致的高能耗问题。High energy consumption is a main problem in using electrochemical descaling system to treat with industrial circulating cooling water.A serrated cathode can help the system to reduce the energy consumption to as low as 6.82 kW·h/kg CaCO_(3).Experimental and numerical simulation results show that the decrease of energy consumption of the system is due to high scale deposition reaction rate at the tip of the serrated cathode,which reduce the adhesion between scale layer and cathode.The scale layer easily falls off from cathode surface,which is beneficial to cathode regeneration.In addition,after the scale layer covers tip area,the deposition reaction of the scale layer gradually shifts from tip area to flat area,which greatly delays cathode’s deactivation and reduces the energy consumption of the electrochemical descaling system.The high energy consumption problem caused by cathode deactivation can be effectively solved through the synergy of tip region and flat area.

关 键 词：阴极 电化学除垢 能源消耗 循环冷却水 

分 类 号：O646.54[理学—物理化学]