从四方到立方:高性能太阳能电池的钙钛矿相结构演变  

From tetragonal to cubic:perovskite phase structure evolution for high-performance solar cells

作　　者：魏旗 梁昊 Yuki Haruta Makhsud Saidaminov 米启兮 Michael Saliba 崔光磊 宁志军 Qi Wei;Hao Liang;Yuki Haruta;Makhsud Saidaminov;Qixi Mi;Michael Saliba;Guanglei Cui;Zhijun Ning(School of Physical Science and Technology,ShanghaiTech University,Shanghai 201210,China;High Performance Computing Department,National Supercomputing Center in Shenzhen,Shenzhen 200441,China;Department of Chemistry and Department of Electrical&Computer Engineering and Centre for Advanced Materials and Related Technologies(CAMTEC),University of Victoria,Victoria V8P 5C2,Canada;Institute for Photovoltaics,University of Stuttgart,Stuttgart 70569,Germany;Qingdao Industrial Energy Storage Research Institute,Qingdao Institute of Bioenergy and Bioprocess Technology,Chinese Academy of Sciences,Qingdao 266101,China)

机构地区：[1]School of Physical Science and Technology,ShanghaiTech University,Shanghai 201210,China [2]High Performance Computing Department,National Supercomputing Center in Shenzhen,Shenzhen 200441,China [3]Department of Chemistry and Department of Electrical&Computer Engineering and Centre for Advanced Materials and Related Technologies(CAMTEC),University of Victoria,Victoria V8P 5C2,Canada [4]Institute for Photovoltaics,University of Stuttgart,Stuttgart 70569,Germany [5]Qingdao Industrial Energy Storage Research Institute,Qingdao Institute of Bioenergy and Bioprocess Technology,Chinese Academy of Sciences,Qingdao 266101,China

出　　处：《Science Bulletin》2023年第2期141-145,M0003,共6页科学通报（英文版）

基　　金：financial support from the National Natural Science Foundation of China(61935016,92056119,and 22175118);the National Key Research and Development Program of China(2021YFA0715502);the Double First-Class Initiative Fund of Shanghai Tech University,and Science and Technology Commission of Shanghai Municipality(20XD1402500,and 20JC1415800);Canada’s Natural Sciences and Engineering Research Council(RGPIN-2020-04239);the German Research Foundation(DFG)for funding(SPP2196,431314977/GRK 2642);Project Proper Photo Mile supported under the umbrella of SOLARERA.NET Cofund 2 by The Spanish Ministry of Science and Education;the AEI under the project PCI2020-112185 and CDTI project number IDI-20210171;the Federal Ministry for Economic Affairs and Energy on the basis of a decision by the German Bundestag(FKZ 03EE1070B and FKZ 03EE1070A);the Israel Ministry of Energy(220-11-031);SOLARERA.NET is supported by the European Commission within the EU Framework Programme for Research and Innovation HORIZON 2020(Cofund ERA-NET Action,No.786483);the Japan Society for the Promotion of Science(JSPS)Overseas Research Fellow program for their financial support。

摘　　要：Crystal structure, which is generally determined by the composition, ionic radius and valence state of constituent elements, plays a significant role in the material’s fundamental properties such as optical, electronic, and mechanical characters. The manipulation of the crystal structure through compositional engineering, and understanding the relationship between crystal structure and properties are essential for the development of materials.

关 键 词：太阳能电池 结构演变 钙钛矿相 

分 类 号：TM914.4[电气工程—电力电子与电力传动]