雀舌黄杨中生物碱成分的研究  

Study on the Alkaloids from Buxus bodinieri

作　　者：闫玉鑫 杨颖 陈方圆 赵燕 沈瑶 YAN Yuxin;YANG Ying;CHEN Fangyuan;ZHAO Yan;SHEN Yao(College of Vocational and Technical Education,Yunnan Normal University,Kunming 650092,China)

机构地区：[1]云南师范大学职业技术教育学院应用化学系,云南昆明650092

出　　处：《云南师范大学学报（自然科学版）》2023年第1期63-67,共5页Journal of Yunnan Normal University:Natural Sciences Edition

基　　金：国家自然科学基金资助项目(82003616);国家大学生创新创业计划资助项目(202110681001,202210681064X)。

摘　　要：用甲醇溶剂对黄杨科黄杨属雀舌黄杨(Buxus bodinieri)的地上部分进行回流提取,采用硅胶、氧化铝、葡聚糖凝胶和半制备HPLC对提取物进行分离纯化,根据理化性质及波谱数据以及与文献数据的比对,从中分离鉴定了10个生物碱化合物,分别为cyclobuxoviridine(1)、N-dimethylcycloxobuxovircine(2)、cyclovirobuxine C(3)、cyclovirobuxine A(4)、cycloprotobuxine C(5)、cycloprotobuxine A(6)、cyclobuxoxazine(7)、cyclobuxoxazine A(8)、buxruguline B(9)和irehine(10).化合物1~9为三萜生物碱,化合物10为甾体生物碱,化合物1及3~10为首次从该植物中分离得到.Various techniques were used to study the chemical constituents of the plant Buxus bodinieri.Ten alkaloids were isolated from their stems and leaves,which were identified as cyclobuxoviridine(1),N-dimethylcycloxobuxovircine(2),cyclovirobuxine C(3),cyclovirobuxine A(4),cycloprotobuxine C(5),cycloprotobuxine A(6),cyclobuxoxazine(7),cyclobuxoxazine A(8),buxruguline B(9),irehine(10).Compounds 1 and 3~10 were first isolated from this plant.

关 键 词：黄杨科 雀舌黄杨 三萜生物碱 甾体生物碱 

分 类 号：Q946[生物学—植物学] R284[医药卫生—中药学]