含氟烯烃的C-F官能化反应研究进展  

Research Progress on the C-F Functionalization of Fluoroolefin

作　　者：张广宇 李伟[1,2] 王飞 何双材 倪航 ZHANG Guang-yu;LI Wei;WANG Fei;HE Shuang-cai;NI Hang(Zhejiang Research Institute of Chemical Industry Co.,Ltd.,Hangzhou,Zhejiang 310023,China;State Key Laboratory of Fluorinated Greenhouse Gases Replacement and Control Treatment,Hangzhou,Zhejiang 310023,China)

机构地区：[1]浙江省化工研究院有限公司,浙江杭州310023 [2]含氟温室气体替代及控制处理国家重点实验室,浙江杭州310023

出　　处：《浙江化工》2023年第2期1-8,12,共9页Zhejiang Chemical Industry

摘　　要：综述了含氟烯烃类化合物的多种官能化方法,主要包括烷基化与全氟烷基化反应,总结了目前含氟烯烃衍生化反应的研究成果,为今后浸没式液冷工质的分子设计与改良提供新的思路。This paper reviews a variety of functionalization methods of fluoroolefin-containing compounds, mainly including alkylation and perfluoroalkylation reactions, summarizes the current research results of fluoroolefin derivatization reactions, and provides new ideas for the molecular design and improvement of immersion liquid-cooled working fluids in the future.

关 键 词：含氟烯烃 C-F官能化 亲核烯基取代反应 衍生化 液冷工质 

分 类 号：TB64[一般工业技术—制冷工程] O621.25[理学—有机化学]