Chemical order-disorder nanodomains in Fe_(3)Pt bulk alloy  

作　　者：Qiang Li Yang Ren Qinghua Zhang Lin Gu Qingzhen Huang Hui Wu Jing Sun Yili Cao Kun Lin Xianran Xing 

机构地区：[1]Beijing Advanced Innovation Center for Materials Genome Engineering,Institute of Solid State Chemistry,University of Science and Technology Beijing,Beijing 100083,China [2]X-Ray Science Division,Argonne National Laboratory,Argonne,IL 60439,USA [3]Beijing National Laboratory for Condensed Matter Physics,Institute of Physics,Chinese Academy of Sciences,Beijing 100190,China [4]NIST Center for Neutron Research,National Institute of Standards and Technology,Gaithersburg,MD 20899-6102,USA

出　　处：《National Science Review》2022年第12期205-213,共9页国家科学评论（英文版）

基　　金：supported by the National Key R&D Program of China(2020YFA0406202);the National Natural Science Foundation of China(22175018,22090042 and 21731001);the China Postdoctoral Science Foundation(2019M660446);the Program for Postdoctoral Innovative Talents(BX20190031);Fundamental Research Funds for the Central Universities(FRF-NP-18-003).

摘　　要：Chemical ordering is a common phenomenon and highly correlated with the properties of solid materials.By means of the redistribution of atoms and chemical bonds,it invokes an effective lattice adjustment and tailors corresponding physical properties.To date,however,directly probing the 3D interfacial interactions of chemical ordering remains a big challenge.In this work,we deciphered the interlaced distribution of nanosized domains with chemical order/disorder in Fe_(3)pt bulk alloy.HAAD F-STEM images evidence the existence of such nanodomains.The reverse Monte Carlo method with the X-ray pair distribution function data reveal the 3D distribution of local structures and the tensile effect in the disordered domains at the single-atomic level.The chemical bonding around the domain boundary changes the bonding feature in the disordered side and reduces the local magnetic moment of Fe atoms.This results in a suppressed negative thermal expansion and extended temperature range in Fe_(3)Pt bulk alloy with nanodomains.Our study demonstrates a local revelation for the chemical order/disorder nanodomains in bulk alloy.The understanding gained from atomic short-range interactions within the domain boundaries provides useful insights with regard to designing new functional compounds.

关 键 词：Fe_(3)Pt alloy chemical order nanodomain local structure pair distribution function 

分 类 号：O469[理学—凝聚态物理]