咪唑基配体及其金属配合物的合成与应用  

Synthesis and Application of Imidazolyl-based Ligand and its Metal Complexes

作　　者：邢宇博 袁守怡 张英杰[1] 董鹏[1] XING Yu-bo;YUAN Shou-yi;ZHANG Ying-jie;DONG Peng

机构地区：[1]锂离子电池及材料制备技术国家地方联合工程研究中心,昆明理工大学冶金与能源工程学院,云南昆明650093

出　　处：《有色设备》2023年第1期42-71,共30页Nonferrous Metallurgical Equipment

基　　金：国家自然科学基金项目(52204312);云南省基础研究重点项目(202101AS070020)。

摘　　要：咪唑及其衍生物作为一类重要的配体分子,可以通过不同的配位模式与众多主体金属离子作用,形成主体-客体配合物。同时,这些配合物在离子识别、荧光材料、药物设计、磁性材料、自组装、气体吸附和催化剂的研发等领域展现出广阔的应用前景。本文着重综述了咪唑基衍生物配体及其配合物的研究进展,对一些此类新型配合物的合成方法与应用做了详细介绍,并展望了未来发展的方向。As a kind of extremely imperative ligand molecules,complexes containing the imidazolyl and its derivatives,can form host-guest compound with a considerable number of host metallic ions by differ-ent coordination modes.Simultaneously,these compound show extensive application prospect in many fields,such as ion recognition,fluorescent material,drug design,magnetic material,self-assembly,gas adsorption and catalyst exploitation.The present review mainly focused on the research progress of com-plexes containing the imidazolyl and its derivatives during,with details regarding with the synthetic meth-ods and applications of novel compounds,proposing the prospects for future development trend.

关 键 词：咪唑衍生物 配位模式 有机金属化学 配合物 

分 类 号：O614[理学—无机化学] O614.8[理学—化学] O626.2